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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
06 January 2017 to 31 January 2017
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment
Qualifier:
according to guideline
Guideline:
other: UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Test H.4
Deviations:
no
GLP compliance:
no
Key result
Relative self-ignition temperature:
> 75 °C
Remarks on result:
no self ignition observed under the test conditions

The sample was observed to take 119.8 hours to reach a temperature 2 °C below the oven temperature. Over the following 168 hours the sample temperature remained level at 73 °C. The sample did not reach a temperature of more than 6 °C above the oven temperature therefore the SADT of the sample is > 75 °C. The substance is therefore exempt from classification as a self-reactive substance of UN Class 4, Division 4.1.

Conclusions:
Under the conditions of this study the test material is exempt from classification as a self-reactive substance of UN Class 4, Division 4.1.
Executive summary:

The self-accelerating decomposition temperature of the test material was investigated according to the method described in the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Test H.4.

The sample was observed to take 119.8 hours to reach a temperature 2 °C below the oven temperature. Over the following 168 hours the sample temperature remained level at 73 °C. The sample did not reach a temperature of more than 6 °C above the oven temperature therefore the SADT of the sample is > 75 °C.

Under the conditions of this study the test material is exempt from classification as a self-reactive substance of UN Class 4, Division 4.1.

Description of key information

Under the conditions of this study the test material is exempt from classification as a self-reactive substance of UN Class 4, Division 4.1.

Key value for chemical safety assessment

Additional information

The self-accelerating decomposition temperature of the test material was investigated according to the method described in the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Test H.4. The study was awarded a reliability score of 2 in accordance with the criteria set forth by Klimisch et al. (1997).

The sample was observed to take 119.8 hours to reach a temperature 2 °C below the oven temperature. Over the following 168 hours the sample temperature remained level at 73 °C. The sample did not reach a temperature of more than 6 °C above the oven temperature therefore the SADT of the sample is > 75 °C.

Under the conditions of this study the test material is exempt from classification as a self-reactive substance of UN Class 4, Division 4.1.