4-benzyloxy-2-nitro-beta-pyrrolidinostyrene

Oxidising properties

Administrative data

Endpoint:

oxidising solids

Type of information:

experimental study

Adequacy of study:

key study

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2017

Report date:

2017

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.17 (Oxidising Properties (Solids))

Version / remarks:

-

Deviations:

no

GLP compliance:

no

Test material

Test material information

Constituent 1

Reference substance name:

Pyrrolidine, 1-[2-[2-nitro-4-(phenylmethoxy)phenyl]ethenyl]-

Cas Number:

99474-22-3

Molecular formula:

C19H20N2O3

IUPAC Name:

Pyrrolidine, 1-[2-[2-nitro-4-(phenylmethoxy)phenyl]ethenyl]-

Specific details on test material used for the study:

- Analytical purity: > 98.4%
 - Lot/batch No.: 0159115
 - Expiration date of the lot/batch: 21/02/2018

Study design

Contact with:

powdered cellulose

Results and discussion

Test results (Oxidising solids)

Test results (Oxidising solids) 1

Sample tested:

reference mixture as specified

Remarks:

Ba(NO3)2 50%

Parameter:

burning rate

Result:

ca. 3.25 mm/s

Remarks on result:

other:

Remarks:

mixture showing th highest burning rate

Test results (Oxidising solids) 2

Sample tested:

test mixture as specified

Remarks:

20% test substance

Parameter:

burning rate

Result:

ca. 3.32 mm/s

Remarks on result:

other:

Remarks:

mixture showing the highest burning rate

Test results (Oxidising solids) 3

Key result

Sample tested:

inert atmosphere

Parameter:

other: ignition

Remarks on result:

other: The mixture did not ignite under argon

Any other information on results incl. tables

Observations

All reference substance mixtures showed clear signs of oxidising properties (cracks, sparkling).

All test substance mixture burned with orange soot emitting flame and carbonized.

Burning Rates Reference Substance

In the following table, the measured data of the reference substance are presented.

Burning Rate of Reference Substance Mixtures

% Ba(NO3)2	Burning Time (s)	Burning Rate (mm/s)
50	66.03	3.03
60	61.47	3.25
70	75.32	2.66

Burning Rates Test Substance

In the following table, the measured data of the test substance mixtures are presented.

Burning Rate of Test substance Mixtures

% Test Substance	Burning Time (s)	Burning Rate (mm/s)
10	70.65	2.83
20	60.16	3.32
30	60.43	3.31
40	64.17	3.12
50	71.20	2.81
60	80.18	2.49
70	86.62	2.31
80	88.97	2.25
90	88.75	2.25

 

The mixture with 20 % test substance IMEXINE OBA/50 SEC shows the highest burning rate.

The burning rate surpasses the burning rate of the reference mixture with the highest burning rate. Therefore the test substance mixture was operated under argon. The mixture did not ignite. Therefore, the study was terminated and the test substance was considered to have no oxidising properties.

Result

The mixture 20% test substance IMEXINE OBA/50 SEC showed a higher burning rate as the burning rate of the reference mixture. But the result was a false positive value. Therefore the test substance mixture was operated under argon. The mixture did not ignite. Therefore, the study was terminated and the test substance was considered to haveno oxidising properties.

Applicant's summary and conclusion

Interpretation of results:

GHS criteria not met

Conclusions:

The mixture 20% test substance IMEXINE OBA/50 SEC showed a higher burning rate as the burning rate of the reference mixture. But the result was a false positive value. There-fore the test substance mixture was operated under argon. The mixture did not ignite. Therefore, the study was terminated and the test substance was considered to have no oxidising properties.

Executive summary:

The oxidising properties of the test item (solid) was determined with a not-GLP compliant study, following the EU method A.17.

The mixture 20% test substance IMEXINE OBA/50 SEC showed a higher burning rate as the burning rate of the reference mixture. But the result was a false positive value, as the miwture did not ignite when the test was operated under argon. Therefore the test substance mixture was operated under argon. The mixture did not ignite. Therefore, the study was terminated and the test substance was considered to have no oxidising properties.