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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed according EC guideline

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1997
Report date:
1997

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
-
EC Number:
427-720-1
EC Name:
-
Cas Number:
26364-65-8
Molecular formula:
C4H5N3S
IUPAC Name:
[(1,3-thiazolidin-2-ylidene)amino]formonitrile
Details on test material:
name: Cyanamide, (4,5-dihydroxy-2-thiazolyl)-
molecular formula: C4 H5 N3 S
molecular weight: 127.2
physical state: solid
analytical purity: 99.8 %

Results and discussion

Any other information on results incl. tables

An exothermic reaction started at 119°C and continued to 132°C. The temperature maximum reached 129°C. It was followed by endothermic and exothermic reaction. The exothermic reaction did not reach the limit temperature of 400°C.

Applicant's summary and conclusion

Conclusions:
The substance does not undergo spontaneous combustion according to EC Guideline A.16 and is not subject to classification.
Executive summary:

CIT does not undergo spontaneous combustion in the sense of EC Guideline A 16. The test substance showed an exothermal reaction starting at 119°C and ending at 132°C. The sample temperature did not reach the limit temperature of 400°C.

CIT does undergo spontaneous combustion in 1 Ltr. Bowes-Cameron-Cage-Test in the sense of RID-, ADR- and UN-Recommendations on the transport of dangerous goods. The maximum reaction temperature was 274°C.

CIT does undergo spontaneous combustion in 16 mL Bowes-Cameron-Cage-Test in the sense of RID-, ADR- and UN-Recommendations on the transport of dangerous goods. The maximum reaction temperature was 230°C.