Registration Dossier

Administrative data

First-aid measures

General notes
Take off immediately all contaminated clothing.
In all cases of doubt, or when symptoms persist, seek medical advice.
Following inhalation
Provide fresh air.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions.
Following skin contact
Rinse skin with water/shower.
Wash with plenty of soap and water.
Following eye contact
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Following ingestion
Rinse mouth. Do not induce vomiting.
Get medical advice/attention if you feel unwell.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
water, foam, alcohol resistant foam, fire extinguishing powder
Unsuitable extinguishing media
water jet

Special hazards arising from the substance or mixture
Hazardous decomposition products: Section 10.
Deposited combustible dust has considerable explosion potential.
Hazardous combustion products
carbon monoxide (CO), carbon dioxide (CO2)

Advice for firefighters
In case of fire and/or explosion do not breathe fumes.
Co-ordinate firefighting measures to the fire surroundings.
Do not allow firefighting water to enter drains or water courses.
Collect contaminated firefighting water separately.
Fight fire with normal precautions from a reasonable distance.
Special protective equipment for firefighters
use suitable breathing apparatus

Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Remove persons to safety.
Ventilate affected area.
Wearing of suitable protective equipment (including personal protective equipment referred to under
Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing.
For emergency responders
Wear breathing apparatus if exposed to vapours/dust/spray/gases.

Environmental precautions
Keep away from drains, surface and ground water.
Retain contaminated washing water and dispose of it.
If substance has entered a water course or sewer, inform the responsible authority.

Methods and material for containment and cleaning up
Advices on how to contain a spill
take up mechanically
Advices on how to clean up a spill
Take up mechanically.
Collect spillage.
Other information relating to spills and releases
Place in appropriate containers for disposal.
Ventilate affected area.

Handling and storage

Precautions for safe handling
Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation.
Keep away from sources of ignition - No smoking.
Specific notes/details
Dust deposits may accumulate on all deposition surfaces in a technical room.
Measures to protect the environment
Avoid release to the environment.
Advice on general occupational hygiene
Do not eat, drink and smoke in work areas.
Wash hands after use.
Preventive skin protection (barrier creams/ointments) is recommended.
Remove contaminated clothing and protective equipment before entering eating areas.

Conditions for safe storage, including any incompatibilities
Explosive atmospheres
Removal of dust deposits.
Flammability hazards
None.
Incompatible substances or mixtures
Incompatible materials: see Stability and reactivity
Protect against external exposure, such as
heat, humidity, UV-radiation/sunlight
Consideration of other advice
Keep away from food, drink and animal feedingstuffs.
Ventilation requirements
Provision of sufficient ventilation.
Specific designs for storage rooms or vessels
Storage temperature recommended storage temperature: <20 °C
Packaging compatibilities
Only packagings which are approved (e.g. acc. to ADR) may be used.

Transport information

Land transport (ADR/RID)

UN number:
3226
Proper shipping name and description:
UN3226, SELF-REACTIVE SOLID TYPE D, (1,1'-AZODI(HEXAHYDROBENZONITRILE)), 4.1, (D), environmentally
hazardous
Chemical name:
1,1'-AZODI(HEXAHYDROBENZONITRILE)
Language:
English
Class:
4.1
Classification code:
SR1
Packaging group:
not assigned to a packing group
Labels:
4.1, fish and tree
Special Provisions:
Provisions for dangerous goods (ADR) should be complied within the premises.
Remarks:
Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.

Inland waterway transport (ADN(R))

UN number:
3226
Proper shipping name and description:
UN3226, SELF-REACTIVE SOLID TYPE D, (1,1'-AZODI(HEXAHYDROBENZONITRILE)), 4.1, (D), environmentally
hazardous
Chemical name:
1,1'-AZODI(HEXAHYDROBENZONITRILE)
Language:
English
Class:
4.1
Classification code:
SR1
Packaging group:
not assigned to a packing group
Labels:
4.1, fish and tree
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3226
Proper shipping name and description:
UN3226, SELF-REACTIVE SOLID TYPE D, (1,1'-AZODI(HEXAHYDROBENZONITRILE)), 4.1, MARINE
POLLUTANT
Chemical name:
1,1'-AZODI(HEXAHYDROBENZONITRILE)
Class:
4.1
Packaging group:
not assigned to a packing group
EmS code:
F-J, S-G
Labels:
4.1, fish and tree
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3226
Proper shipping name and description:
UN3226, Self-reactive solid type D, (1,1'-AZODI(HEXAHYDROBENZONITRILE)), 4.1
Chemical name:
1,1'-AZODI(HEXAHYDROBENZONITRILE)
Class:
4.1
Packaging group:
not assigned to a packing group
Labels:
4.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls
Appropriate engineering controls
General ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection
Wear eye/face protection.
Hand protection
Protective gloves
Wear suitable gloves.
Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use.
In the case of wanting to use the gloves again, clean them before taking off and air them well.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Particulate filter device (EN 143).

Environmental exposure controls
Use appropriate container to avoid environmental contamination.
Keep away from drains, surface and ground water.

Stability and reactivity

Reactivity
Self-reactive property.
If heated:
risk of ignition

Chemical stability
See below "Conditions to avoid".

Possibility of hazardous reactions
No known hazardous reactions.

Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
The product in the delivered form is not dust explosion capable; the enrichment of fine dust however
leads to the danger of dust explosion.

Incompatible materials
oxidisers

Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill
and heating are not known.

Disposal considerations

Waste treatment methods
This material and its container must be disposed of as hazardous waste.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
Handle contaminated packages in the same way as the substance itself.
Remarks
Please consider the relevant national or regional provisions.