Registration Dossier
Registration Dossier
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Diss Factsheets
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EC number: 213-834-7 | CAS number: 1025-15-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered. Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Potential for exposure by inhalation if aerosols or mists are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor if the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
Ingestion:
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed:
Symptoms:
daze, headache, dizziness, somnolence (drowsiness), nausea.
May cause lung damage if swallowed.
Health injuries may be delayed.
Hazards:
Harmful in contact with skin and if swallowed.Vapours may cause drowsiness and dizziness.
Indication of any immediate medical attention and special treatment needed:
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the noxious substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
Continue with first aid measures.
Depending on the pathology and clinical findings, patient monitoring and symptomatic treatment are necessary.
Fire-fighting measures
Suitable extinguishing media:
Water, mist, dry powder, foam
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
Danger of decomposition under influence of heat.
Hazard-determining flue gases might develop in case of fire:
Hydro-cyanic acid, Carbon monoxide.
Risk determining decomposition products: Allylamine.
Special protective equipment for fire-fighters:
In the event of fire, wear self-contained breathing apparatus.
Full protective suit.
Advice for firefighters:
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
In case of fire cool containers or take them to a safe place.
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Take precautionary measures against static discharges.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Fire residues should be disposed of in accordance with the regulations.
Keep out unprotected persons.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Keep unauthorized persons away.
Environmental precautions:
Prevent substance from entering soil, natural bodies of water and sewer systems.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material, e. g.: diatomaceous earth sand universal binder.
Dispose of absorbed material in accordance with the regulations.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.
Reference to other sections:
Wear personal protective equipment; see section 8.
Handling and storage
Handling:
Precautions for safe handling:
Wear personal protective equipment.
Handle in accordance with good industrial hygiene and safety practices.
Keep in a dry, cool place.
Avoid residues of the product on the containers.
If the material has to be melted we recommend a water bath with a maximum temperature of 50 °C.
Heated chambers are also permissible.
Advice on protection against fire and explosion:
Normal measures for preventive fire protection.
Dust explosion class:
Not applicable.
Storage:
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions. Well ventilated.
Further information:
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
Storage capability limited; dependent on Storage conditions.
Advice on common storage:
Observe prohibition against storing together!
German storage class:
Combustible / non-combustible liquids and solids not assigned to other storage classes.
Dust explosion class
Not applicable.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Additional transport information
Additional information
- Special provisions / remarks / other:
- Combination traffic :
Labelling of containers / shipping units following main product run as per sea or air transport regulations.
Exposure controls / personal protection
Control parameters:
Engineering measures:
Ensure suitable suction/aeration at the work place and with operational machinery.
Provide for installation of emergency shower and eye bath.
Personal protective equipment:
Respiratory protection:
Use suitable respiratory protection where aerosols/vapours are generated.
When handling for a short time: Respirator with brown A-type filter.
In the event of prolonged exposure during handling: Respirator with ABEK-P2 combination filter.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Applies to handling for brief periods or of small amounts:
Glove material: Nitrile, for example, Dermatril P 743, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.20 mm
Method: DIN EN 374
Applies to handling for longer periods or of large amounts:
Glove material: Chloroprene, for example: Camapren 720, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.65 mm
Method: DIN EN 374
Eye protection:
safety glasses with side-shields conforming to EN166 or when handling larger quantities: basket-shaped glasses.
Skin and body protection:
Usual lab protective clothing or when handling larger quantities: chemical protective suit, disposable protective suit.
Hygiene measures:
Remove and wash contaminated clothing before re-use.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Avoid contact with skin, eyes and clothing.
Apply adequate skin protection agents before handling the product.
Cleanse and apply cream to skin after work. Preventive skin protection recommended.
Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used.
Stability and reactivity
Chemical Stability:
The product is chemically stable.
Possibility of hazardous reactions:
Risk of a polymerisation triggered by exothermic reaction above 70 °C.
Conditions to avoid:
Avoid temperatures in excess of 60°C for longer periods.
Incompatible materials:
Radical producers such as peroxides, azo compounds.
Disposal considerations
Product:
Disposal according to local authority regulations.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.