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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2019-03-13 - 2019-03-13
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Version / remarks:
Commission Regulation (EC) No 440/2008 of 30. May 2008, published on 31. May 2008, Method A.16: "Relative Self-Ignition Temperature for Solids"
Deviations:
yes
Remarks:
The heating rate slightly deviated from the value stated in the guideline of 0.5 °C/min (0.58 °C/min). This is considered as uncritical as a nominal heating rate of 0.5 °C/min was adjusted at the instrument and only a minimal deviation was observed.
GLP compliance:
yes (incl. QA statement)
Key result
Relative self-ignition temperature:
> 250 °C
Remarks on result:
no self-ignition observed up to the melting point
Conclusions:
The study was conducted under GLP according to EU Method A.16 without minor deviations and therefore reliability of Klimisch 1 has been assigned. Based on the obtained results the test item Magnesium perchlorate should be considered as "showing no self-ignition up to the melting point of 250°C" under the test conditions.
Executive summary:

The determination of the relative self ignition temperature of Magnesium perchlorate was performed under GLP according to EU Method A.16.

The relative self ignition temperature of Magnesium Perchlorate was determined by placing the test item into a stainless steel cube and heating from room temperature to an oven temperature of 255 °C with the ZPA-3 oven.

No increase in the temperature of the sample in comparison to that of the oven could be detected, also no signs of ignition could be observed.

Therefore, the test item Magnesium Perchlorate should be considered as "showing no self-ignition up to the melting point of 250°C" under the test conditions.

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Description of key information

no self-ignition up to the melting point of 250°C" under test conditions (EU Method A.16., GLP)

Key value for chemical safety assessment

Additional information