Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
General advice
Remove contaminated clothing immediately. Medical treatment is necessary if symptoms are evidently caused by the effects on the skin, or the eyes, or by inhalation of its dust.
Inhalation
Move subject to fresh air and keep him calm. In case of complaints get medical treatment.
Skin contact
Wash off immediately with soap and water. If skin irritation occurs consult a physician.
Eye contact
In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. See a physician.
Ingestion
Contact a doctor immediately.

4.2. Most important symptoms and effects, both acute and delayed
Acute dermal irritation/corrosion, Acute eye irritation/corrosion, Eye damage, central nervous system effects characterized by headache, drowsiness and dizziness, gastrointestinal irritation with nausea, vomiting and diarrhea

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media water spray, foam, dry chemical, carbon dioxide
Extinguishing media which must not
be used for safety reasons
full water jet

5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.

5.3. Advice for firefighters
Wear self-contained breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Take care for adequate ventilation. Use personal protective clothing. Use breathing apparatus if exposed to
vapours/dust/mist/aerosol.

6.2. Environmental precautions
Prevent product from getting into drains/surface water/groundwater.

6.3. Methods and material for containment and cleaning up
Take up mechanically. Dispose of in accordance with regulations.

6.4. Reference to other sections
For personal protection see section 8.

Handling and storage

7.1. Precautions for safe handling
Safe handling advice Avoid the formation and deposition of dust. Provide extraction if dust raised. Keep
container tightly closed.
Advice on protection against fire and explosion
Avoid dust formation. In the event of fire, cool the endangered containers with water. Take precautionary measures against static discharges.

7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Store in a well-ventilated place. Keep container tightly closed. Keep only in the
original container at a temperature not exceeding 30 °C. Protect from light.
Advice on common storage Do not store together with acids or alkalis. Do not store together with strong
oxidizing agents.

7.3. Specific end use(s)
no

Transport information

Land transport (ADR/RID)

Shippingopen allclose all
Remarks:
Not a dangerous good within the meaning of transportation regulations.

Inland waterway transport (ADN(R))

Shippingopen allclose all
Remarks
Not a dangerous good within the meaning of transportation regulations.

Marine transport (IMDG)

Remarks
Not a dangerous good within the meaning of transportation regulations.

Air transport ICAO/IATA

Remarks
Not a dangerous good within the meaning of transportation regulations.

Additional transport information

Additional transport information
Not a dangerous good within the meaning of transportation regulations.

Exposure controls / personal protection

An occupational Exposure Limit-value is not established (2007).
Occupational exposure controls
For monitoring procedures refer to for instance "Empfohlene Analysenverfahren für Arbeitsplatzmessungen" Schriftenreihe der Bundesanstalt für Arbeitsschutz und "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health

8.1. Control parameters
see section 8.2.

8.2. Exposure controls
Protective measures
Do not inhale dust. Avoid contact with eyes and skin.

Hygiene measures
Store work clothing separately. Remove soiled or soaked clothing immediately.
Follow the usual good standards of occupational hygiene. Clean skin thoroughly
after work; apply skin cream.

Respiratory protection
respiratory protection in case of dust formation, short term: filter appliance, filter P2

Hand protection
butyl rubber gloves (0.7 mm), Break through time 300 min (EN 374)
In practice, due to variable exposure conditions, this information can only be an aid
to orientation for the selection of a suitable chemical protection glove. In particular,
this information does not substitute suitability tests by the end user.

General information
Gloves should be replaced regularly, especially after extended contact with the
product. For each work-place a suitable glove type has to be selected.

Eye protection
tightly fitting goggles

Stability and reactivity

10.1. Reactivity
see section 10.2.

10.2. Chemical Stability
No decomposition when used as directed.

10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing
substances, and/or heavy metal ions.
persulfate

10.4. Conditions to avoid
The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is
exceeded, the product may polymerize with heat evolution.

10.5. Incompatible materials
oxidizing agents
initiator

10.6. Hazardous decomposition products
None when used as directed.

Disposal considerations

13.1. Waste treatment methods
Product Waste is hazardous. It must be disposed of in accordance with the regulations after
consultation of the competent local authorities and the disposal company in a
suitable and licensed facility.
Uncleaned packaging Uncontaminated packaging may be taken for recycling. Contaminated packaging
should be emptied optimally and after appropriate professional cleansing may be
taken for reuse. Packaging that cannot be cleaned should be disposed of
professionally.
Code of waste EWC
07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics, synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.