A mixture of: bis(2,2,6,6-tetramethyl-1-octyloxypiperidin-4-yl)-1,10-decanedioate; 1,8-bis[(2,2,6,6-tetramethyl-4-((2,2,6,6-tetramethyl-1-octyloxypiperidin-4-yl)-decan-1,10-dioyl)piperidin-1-yl)oxy]octane

Guidance on Safe Use

First-aid measures

General information: As a general rule, in case of doubt or if symptoms persist, always call a doctor.Never give anything by mouth to an unconscious person. If unconscious, placein recovery position and seek medical advice.

In case of inhalation: Remove victim to fresh air and keep at rest in a position comfortable and well-ventilated for breathing. In case of irritation of respiratory system or mucous membranes and/or indisposition and/or prolonged exposure, seek medical attention.

In case of skin contact: After contact with skin, wash immediately with plenty of water and soap for several minutes and seek medical advice. Not use organic solvents. Wash contaminated clothing before reusing.

In case of eye contact: Check for and remove any contact lenses. Immediately flush eyes with runningclean water for at least 15 minutes, keeping eyelids open. Obtain emergency medical attention (e.g. contact ophthalmologist) if pain, blinking, tears or redness persist.

In case of ingestion: Immediately give plenty (> 500 ml) of water (if possible charcoal slurry). In case of spontaneous vomiting be sure that vomitus can freely drain due of danger of suffocation. Give water repeatedly. Do not induce vomiting/risk of damage to lungs exceeds poisoning risk. Give nothing by mouth in cases of unconsciousness or convulsion. Get medical attention immediately and show the container or label.

In case of body contact: Remove contaminated clothing. Wash contaminated clothing before reusing.

Self-protection of the first-aiders: No action shall be taken involving any personal risk or without suitable training.

Notes to physician: No specific treatment. Treat symptomatically.

Most important symptoms and effects, both acute and delayed: No specific information.

Indication of any immediate medical attention and special treatment needed: No specific information.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:       Carbon dioxide (CO2), dry powder, foam

Extinguishing media which must not be used for safety reason: High volume water jet.

Special hazards arising from the substance or mixture: Contaminated fire water from fire hoses, sprinkler systems, etc., not enter to water, sewer or into ground water in the flush. To ensure adequate facility for fire water retention. Disposal of contaminated water and soil according to local regulations.

Advice for fire-fighters: Wear full protective clothing. Wear self-contained breathing apparatus.

Hazard decomposition products: Burning may produce toxic combustion products: Carbon oxides, Nitrogen oxides.

Other information: Do not enter fire area without proper protection. Fight fire from safe distance/protected location. Apply aqueous extinguishing media carefully to prevent frothing/steam explosion. Use water spray for cooling. Avoid contact with molten product to prevent serious burns. Avoid raising powdered materials into airborne dust, creating an explosion hazard. Prevent fire-fighting water from entering surface water or groundwater. Contaminated water from fire hoses or sprinkler etc must be prevented from draining into watercourses, sewers or the ground water. Sufficient measures must be taken to retain water used for extinguishing. Contaminated water and soil must be disposed of in conformity with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without suitable training. Remove all sources of ignition. Ventilate area of leak or spill. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spit material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Avoid inhalation of mist or vapour. Avoid contact with eyes and prolonged skin contact. Put on appropriate personal protective equipment (see section 8).

Environmental precautions: Do not flush into surface water, sanitary sewer or ground water system.

Methods and material for containment and cleaning up Spills/Leaks: Remove unnecessary people. Pick up with inert absorbent material (e.g. sand, earth etc.). Place into approved waste containers. Wear suitable protective equipment. Should not be released into the environment. Collect the spilled product into suitable containers which must be tightly sealed and properly labelled.

Handling and storage

Precautions for safe handling:

As a general rule, not to eat, drink and smoke in work areas ; to wash hands after use and; to remove contaminated clothing and protective equipment before entering eating areas.Handling requirement:Substance may cause long lasting harmful effects to aquatic life. Handle and open container with care. In accordance with good industrial practice and avoid unnecessary personal contact. Avoid eye, skin and clothing contact. Do not inhale. Do not taste or swallow. Avoid vapour or mist formation. Use only with adequate ventilation. Keep away from ignition sources. Handle according to industrial hygiene principles and relevant legal provisions.Protection against fire and explosion:No physical hazard determined at this time. Handle this substance in liquid form with care and follow standard industrial practices.Condition and materials to avoid:Direct sunlight, excessive light, moisture, oxidizing conditions, excessively high temperatures, sparks and open flame, dusting conditions.

Conditions for safe storage, including any incompatibilities:       Keep container tightly closed in a dry, cool and well-ventilated place against strong oxidizers when not in use and during transport, prevent contamination with foreign materials. Keep chemical away from direct sunlight, heat, sparks, open flame and other ignition sources. Keep away from food and drink. Store in the original container securely closed. Protect from moisture and physical damage.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

N.A.

Shipping information

Proper shipping name and description:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate
Trade name: Chiguard® 101

Chemical name:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate

Language:

English

Labels:

N.A.

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

N.A.

Shipping information

Proper shipping name and description:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate
Trade name: Chiguard® 101

Chemical name:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate

Language:

English

Labels:

N.A.

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

N.A.

Shipping information

Proper shipping name and description:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate
Trade name: Chiguard® 101

Chemical name:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate

Labels:

N.A.

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

N.A.

Shipping information

Proper shipping name and description:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate
Trade name: Chiguard® 101

Chemical name:

Reaction mass of bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] decanedioate and 1,1'-bis[2,2,6,6-tetramethyl-1-(octyloxy)piperidin-4-yl] 10,10'-{octane-1,8-diylbis[oxy(2,2,6,6-tetramethylpiperidine-1,4-diyl)]} didecanedioate

Labels:

N.A.

Remarks

SpecialProvisions

Exposure controls / personal protection

Appropriate engineering controls: Work in well ventilated areas. Local exhaust ventilation is generally required because it can control the emissions of the contaminant and its source, preventing dispersion of it into the general work area. Exposure limit(s) should be monitored using suitable analytical equipments.

Precautionary and hygiene measures: Precautionary measures: Do not handle this chemical near heat, sparks or open flame. Prevent electrostatic discharge formation. Avoid accumulation of mist or vapour in enclosed space. Keep container closed when not in use. Avoid contact with eyes, skin and clothing. Do not breathe mist or vapour. Use only with adequate ventilation and personal protection. Before using this chemical or products containing this chemical, read eSDS. Hygiene measures:Wash hands, forearms and face thoroughly after handling this chemical or products containing this chemical, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Do not eat, drink or smoke while working. Keep away from foodstuffs, beverages and food. During synthesis, formulation or application, follow good industrial hygiene practice. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.

Respiratory protection: In case of insufficient ventilation, wear suitable respiratory protective equipment, such as NIOSH approved respirator. High levels of protection would also be required for laboratory workers handling the chemical.

Hand protection: Protective gloves (impervious gloves) should be worn at all times when handling chemical products. PVC coated cotton gloves and/or heavy rubber gloves are recommended.

Eye protection: Use tightly fitting safety goggles (chemical goggles) and/or safety mask where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

Skin protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. The skin protection equipments should be cleaned thoroughly after each use.

Body protection: Wear overall, protective clothing, e.g. wear rubber apron, wear rubber footwear/boots.

Stability and reactivity

Reactivity: No specific information

Chemical stability: Stable under ordinary conditions of use and storage. Heat will contribute to instability.Decomposition temperature: > 230 °C

Possibility of hazardous reactions: No hazardous reactions known.

Conditions to avoid: Heat, ignition sources and incompatibilities. Static discharges.

Incompatible materials: Strong acids, strong bases and strong oxidising agents.

Hazardous decomposition products: No decomposition expected under normal storage conditions.Carbon oxides, nitrogen oxides (NOx), Toxic gases / vapours may form when heated to decomposition or in a fire involving this chemical (Start of decomposition 230oC).

10.7 Further information:       Will not occur.

Disposal considerations

Waste treatment methods: The generation of waste should be avoided or minimised wherever possible. Disposal of this substance or product containing this chemical, solutions and any by-products must be dumped or incinerated in accordance with local/regional/national/international regulations.

Waste from residues/unused products: Residual chemical should be disposed by incineration or by other modes or disposal in compliance with local/regional/national/international regulations.

Contaminated packaging: Contaminated packaging material should be treated equivalent to residual chemical. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local/regional/national/international regulations.