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EC number: 432-400-1 | CAS number: 10102-09-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Description of first aid measures
Eye contact:
Get medical attention immediately. Call a poison center or physician.
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Chemical burns must be
treated promptly by a physician.
Inhalation:
Get medical attention immediately. Call a poison center or physician.
Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing apparatus.
If not breathing, if breathing is irregular or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband. In case of inhalation of
decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48
hours.
Skin Contact:
Get medical attention immediately. Call a poison center or physician.
Wash with plenty of soap and water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician. In the event
of any complaints or symptoms, avoid further exposure. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion:
Get medical attention immediately. Call a poison center or physician.
Wash out mouth with water. Remove dentures if any. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If
material has been swallowed and the exposed person is conscious, give
small quantities of water to drink. Stop if the exposed person feels sick
as vomiting may be dangerous. Do not induce vomiting unless directed
to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Chemical burns must
be treated promptly by a physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Protection of first aiders:
: No action shall be taken involving any personal risk or without suitable
training. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing apparatus.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves.
Fire-fighting measures
Extinguishing media
Suitable extinguishing agents: Use an extinguishing agent suitable for the surrounding fire.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture
Oxidising material. May intensify fire. In a fire or if heated, a pressure
increase will occur and the container may burst. This material is very
toxic to aquatic life with long lasting effects. Fire water contaminated
with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Decomposition products may include the following materials:
nitrogen oxides
Advice for firefighters
Promptly isolate the scene by removing all persons from the vicinity of
the incident if there is a fire. Risk of explosion. If large quantities are
involved in a major fire, evacuate the area. No action shall be taken
involving any personal risk or without suitable training. Move containers
from fire area if this can be done without risk. Use water spray to keep
fire-exposed containers cool. Fight fire from protected location or
maximum possible distance
Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in
positive pressure mode. Clothing for fire-fighters (including helmets,
protective boots and gloves) conforming to European standard EN 469
will provide a basic level of protection for chemical incidents.
Accidental release measures
No action shall be taken involving any personal risk or without suitable
training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through spilt
material. Shut off all ignition sources. No flares, smoking or flames in
hazard area. Do not breathe vapour or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.
Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or
air). Water polluting material. May be harmful to the environment if
released in large quantities. Collect spillage.
Small spills:
Stop leak if without risk. Move containers from spill area. Use sparkproof tools and explosion-proof equipment. Dilute with water and mop
up if water-soluble. Do not absorb in sawdust or other combustible
material. It may lead to a fire risk when it dries out. Alternatively, or if
water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Absorb spillage to prevent
material damage. Dispose of via a licensed waste disposal contractor
Large Spills:
Stop leak if without risk. Move containers from spill area. Use sparkproof tools and explosion-proof equipment. Absorb spillage to prevent
material damage. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Do not absorb in
sawdust or other combustible material. It may lead to a fire risk when it
dries out. Wash spillages into an effluent treatment plant or proceed as
follows. Contain and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations. The spilled material
may be neutralized with sodium carbonate, sodium bicarbonate or
sodium hydroxide. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilt
product.
Handling and storage
Handling:
Put on appropriate personal protective equipment..
Persons with a history of skin sensitization problems should not be
employed in any process in which this product is used. Do not get in
eyes or on skin or clothing. Do not breathe vapour or mist. Do not
ingest. Avoid release to the environment. If during normal use the
material presents a respiratory hazard, use only with adequate
ventilation or wear appropriate respirator. Keep in the original container
or an approved alternative made from a compatible material, kept tightly
closed when not in use. Keep away from clothing, incompatible
materials and combustible materials. Keep away from alkalis. Keep
away from heat. Empty containers retain product residue and can be
hazardous. Do not reuse container. Absorb spillage to prevent material
damage.
Store in accordance with local regulations. Store in original container protected from direct sunlight in
a dry, cool and well-ventilated area, away from incompatible materials, food and
drink. Store in corrosive resistant container with a resistant inner liner. Store locked up. Separate
from alkalis. Separate from reducing agents and combustible materials. Store away from grease and
oil. Keep away from metals. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store
in unlabelled containers. Use appropriate containment to avoid environmental contamination. See
Section 10 for incompatible materials before handling or use
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Engineering controls:
If user operations generate dust, fumes, gas, vapour or mist, use
process enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Eye/Face Protection:
Safety eyewear complying with an approved standard should be used
when a risk assessment indicates this is necessary to avoid exposure to
liquid splashes, mists, gases or dusts. If contact is possible, the
following protection should be worn, unless the assessment indicates a
higher degree of protection: chemical splash goggles and/or face shield.
If inhalation hazards exist, a full-face respirator may be required instead.
Hand protection:
Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical products if
a risk assessment indicates this is necessary. Considering the
parameters specified by the glove manufacturer, check during use that
the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures,
consisting of several substances, the protection time of the gloves
cannot be accurately estimated.
Body protection:
Personal protective equipment for the body should be selected based on
the task being performed and the risks involved and should be approved
by a specialist before handling this product.
Respiratory protection:
Based on the hazard and potential for exposure, select a respirator that
meets the appropriate standard or certification. Respirators must be
used according to a respiratory protection program to ensure proper
fitting, training, and other important aspects of use.
Environmental exposure controls:
Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or
engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.
Stability and reactivity
Chemical stability
The material is supplied in a stable condition and other than the previously mentioned catalytic
hazards of this material, no specific reactive hazards are known. The catalytic properties of this
material may give it a low ignition temperature (except when supplied as a paste). The catalytic
properties will also promote the oxidation and possible ignition of flammable liquids and vapours. A
used, filtered catalyst should, therefore, be kept wet and out of contact with combustible vapours
and liquids.
Possibility of hazardous reactions:
Attacks many metals producing extremely flammable hydrogen gas which can form explosive
mixtures with air.
Reactive or incompatible with the following materials:
alkalis
combustible materials
reducing materials
metals
Incompatible materials: Store away from flammable substances. Corrosive action on metals.
Hazardous decomposition products: Nitrogen oxides
Additional information: -
Disposal considerations
Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all
authorities with jurisdiction. Return accumulated waste material to the
refinery for metal recovery, or dispose of in accordance with local and
national regulations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.