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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Partition coefficient

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
partition coefficient
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is inorganic

Description of key information

Log Kow [silicon tetrachloride]: Not relevant, substance is inorganic and also reacts very rapidly in contact with water

Log Kow [silicic acid]: not relevant for inorganics

Key value for chemical safety assessment

Additional information

In accordance with Column 2 of REACH Annex VII, the partition coefficient study does not need to be conducted as silicon tetrachloride and its hydrolysis products, silicic acid and hydrochloric acid are inorganic.

In addition, silicon tetrachloride reacts very rapidly in contact with water, generating monosilicic acid and hydrochloric acid. Monosilicic acid condenses at concentrations above approximately 100-150 mg/L as SiO2 to give insoluble amorphous polysilicic acid.

log Kow is not relevant for inorganic compounds such as silicic acid.

The purpose of the log Kow study is to understand the interaction of the substance with water and octanol, which acts as a model for lipids in humans and organisms and for organic carbon in soils and sediments. On the basis of structure and supported by predictions, monosilicic acid has a high affinity with water and low affinity for lipids and organic carbon. A log Kow value of -4 was determined for monosilicic acid using a QSAR estimation method. The method has not been validated for inorganic substances but gives an indication of very low log Kow.