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Diss Factsheets

Physical & Chemical properties

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Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Study initiation 30th October 2002, Experimental phase 13th November 2002-17th January 2003
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Meets the criteria for classification as Reliable without restriction according to Klimisch et al (1997)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2003
Report date:
2003

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
-
EC Number:
443-510-2
EC Name:
-
Cas Number:
738587-10-5
Molecular formula:
C26H14N10Ni2O18S4 as free acid
IUPAC Name:
dinickel(2+) sodium 3-carboxy-5-[(1E)-2-(7-oxido-2,6-disulfonaphthalen-1-yl)diazen-1-yl]-1H-1,2,4-triazol-1-ide 3-carboxy-5-[(1E)-2-(7-oxido-2-sulfo-6-sulfonatonaphthalen-1-yl)diazen-1-yl]-1H-1,2,4-triazol-1-ide

Results and discussion

Relative self-ignition temperature (solids)
Relative self-ignition temperature:
ca. 355 °C
Remarks on result:
other:
Remarks:
at atm. press. of 101325.0 Pa

Any other information on results incl. tables

The temperature/time trace for this test is shown in Figure 7 (see attached background information)

Comments:

(i) Endothermic activity was detected below 200°C.

(ii) Exothermic activity was detected, during which the sample temperature increased at a rate of approximately BOO°C/minute to attain a maximum temperature of 537°C.

(iii) The test substance attained a temperature of 400°C at an oven air temperature of 355 ± 5°C, which is defined as the Relative Self-Ignition Temperature (RSIT).

(i\l) On inspection after the test, the sample basket was observed to be full of carbonised material.

Applicant's summary and conclusion

Conclusions:
Relative Self-Ignition Temperature = 355 ± 5°C.
Executive summary:

Introduction:

The test was carried out in accordance with EU test method Test A16.

Results and conclusions:

i) Endothermic activity was detected below 200°C.

(ii) Exothermic activity was detected, during which the sample temperature increased at a rate of approximately BOO°C/minute to attain a maximum temperature of 537°C.

(iii) The test substance attained a temperature of 400°C at an oven air temperature of 355 ± 5°C, which is defined as the Relative Self-Ignition Temperature (RSIT).

(i\l) On inspection after the test, the sample basket was observed to be full of carbonised material.

Relative Self-Ignition Temperature = 355 ± 5°C.