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Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
April - 2013
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
comparable to guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2013

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
ASTM E659 (Standard test method for autoignition temperature of liquid chemicals)
Version / remarks:
2005
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Propiononitrile
EC Number:
203-464-4
EC Name:
Propiononitrile
Cas Number:
107-12-0
Molecular formula:
C3H5N
IUPAC Name:
propanenitrile
Test material form:
liquid

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
500 °C
Atm. press.:
101.325 kPa

Any other information on results incl. tables

Detailed Autoignition Temperature Test Data for substance.

Test

Sample Quantity (µL)

Test Temperature (oC)

Ignition delay (s)

Ignition

1

100

484

-

No

2

300

484

-

No

3

100

544

5.3

Yes

4

100

520

-

No

5

300

520

10.3

Yes

6

300

503

-

No

7

500

503

-

No

8

300

510

14

Yes

9

300

506

-

No

10

500

506

21.7

Yes

11

700

503

-

No

12

600

503

-

No

13

400

503

-

No

14

600

508

-

No

15

500

508

-

No

16

400

508

-

No

17

600

515

-

No

18

200

503

24

Yes

19

200

500

25.8

Yes

20

200

497

-

No

21

100

497

-

No

22

200

512

12.7

Yes

23

300

500

-

No

Applicant's summary and conclusion

Conclusions:
The substance demonstrated an auto-ignition temperature of 500 ± 3°C under the experimental conditions employed.
Executive summary:

According to the methodology 'ASTM E659, Standard Test Method for Autoignition Temperature of Liquid Chemicals' the substance has an autoignition at temperature of 500 ± 3°C. It is noteworthy that the autoignition temperature of a substance is highly dependent upon numerous conditions: the concentration of vapor pressure of the system, presence of catalytic material, time window, flow conditions, volume of the test vessel, and initial starting pressure.  Thus, a lower autoignition temperature may be observed in systems with larger volumes, an increase in initial pressure, or an increase in initial oxygen concentration than the apparatus setup used for the current tests.