Registration Dossier
Registration Dossier
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EC number: 203-312-7 | CAS number: 105-59-9
Guidance on Safe Use
Administrative data
First-aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11., Further symptoms are possible
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, alcohol-resistant foam, carbon dioxide
Special hazards arising from the substance or mixture
Endangering substances: nitrogen oxides, carbon oxides
Advice: The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
Protection against fire and explosion:
The product is combustible. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Temperature class: T3 (Autoignition temperature >200 °C).
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Suitable materials for containers: Carbon steel (Iron), Stainless steel 1.4401, Stainless steel 1.4301 (V2), High density polyethylene (HDPE), glass, Low density polyethylene (LDPE)
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage class according to TRGS 510 (originally VCI, Germany): (10) Combustible liquids
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with occupational exposure limits
No substance specific occupational exposure limits known.
PNEC
freshwater: 0,1 mg/l
marine water: 0,0045 mg/l
intermittent release: 1 mg/l
sediment (freshwater): 0,78 mg/kg
sediment (marine water): 0,0351 mg/kg
soil: 0,097 mg/kg
STP: 10 mg/l
oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.
DNEL
worker:
Long-term exposure- systemic effects, Inhalation: 7,9 mg/m3
worker:
Long-term exposure- systemic effects, dermal: 5,6 mg/kg
consumer:
Long-term exposure- systemic effects, Inhalation: 0,4 mg/m3
consumer:
Long-term exposure- systemic effects, dermal: 0,67 mg/kg
consumer:
Long-term exposure- systemic effects, oral: 0,13 mg/kg
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A) Consider the risk management measures as outlined in the exposure scenario.
Hand protection:
Chemical resistant protective gloves (EN ISO 374-1)
Performance level 6, corresponding to a breakthrough time of >480 min according to EN ISO 374-1
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Take off immediately all contaminated clothing. Store work clothing separately.
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
The progress of reaction is exothermic. Reacts with halogenated compounds. Reacts with oxidizing agents. Reacts with acids. Reacts with acid chlorides. Incompatible with acid chlorides and acid anhydrides.
Conditions to avoid
Avoid extreme temperatures. See SDS section 7 - Handling and storage.
Incompatible materials
Substances to avoid:
acid chlorides, acid anhydrides, acid forming substances, acids, oxidizing agents, nitrosating agents
Hazardous decomposition products
Hazardous decomposition products:
carbon oxides, nitrogen oxides, nitrous gases
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
