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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Biodegradation in soil

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Administrative data

Endpoint:
biodegradation in soil
Type of information:
experimental study
Adequacy of study:
other information
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Acceptable, well documented publication which meets basic scientific principles.

Data source

Reference
Title:
No information
Author:
Graveel JG, Sommers LE, Nelson W (1985). Sites of benzidine, alpha-naphthylamine and p-toluidine retention in soils. Environ. Toxicol. Chem. 4, 607-613.

Materials and methods

Principles of method if other than guideline:
radiotracer experiment
GLP compliance:
not specified
Test type:
laboratory

Test material

Constituent 1
Chemical structure
Reference substance name:
p-toluidine
EC Number:
203-403-1
EC Name:
p-toluidine
Cas Number:
106-49-0
Molecular formula:
C7H9N
IUPAC Name:
4-methylaniline
Details on test material:
- Name of test material (as cited in study report): p-Toluidine
- labeled p-toluidine: uniformly 14C-ring-labeled
- unlabeled p-toluidine: Sigma Technical Grade; initial concentration was 0.19 M


Radiolabelling:
yes

Results and discussion

Half-life / dissipation time of parent compound
Type:
(pseudo-)first order (= half-life)
Details on results:
Extracted amines at day zero:
a) EtAc-MeOH: 67%
b) NH4OAc: 12.3%
c)NaOH: 8.4%
Sum: 87.7%

Extracted amines after 63 d incubation period:
a) EtAc-MeOH: 13.0% +/- 4.5%
b) H4OAc: 3.1% +/-0.4%
c) NaOH: 31.8% +/-2.5%
Sum: 47.9%

Decomposition of p-toluidine was low (ca. 15% CO2 evolution of added conc.)

Any other information on results incl. tables

The extraction at day zero indicates that p-toluidine was initially loosely associated with clay and organic matter through electrostatic interactions, hydrophobic bonding or reversible amine linkages with humate carbonyls (reported soil pH of approx. 5 resulted in protonation of p-toluidine). The increase of p-toluidine in the NaOH fraction until day 63 suggests that the amine is increasingly covalently linked to humic components in soil.

Applicant's summary and conclusion