Registration Dossier
Registration Dossier
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EC number: 433-460-1 | CAS number: 210880-92-5
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely.
Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.
Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
No symptoms known or expected.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote.
Fire-fighting measures
5.1 Extinguishing media
Suitable
Water spray, Carbon dioxide (CO2), Foam, Sand
5.2 Special hazards arising from the substance or mixture
In the event of fire the following may be released:, Hydrogen chloride (HCl), Hydrogen cyanide (hydrocyanic acid), Carbon monoxide (CO), Sulphur oxides, Nitrogen oxides (NOx)
5.3 Advice for firefighters
Special protective equipment for firefighters
In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.
Further information
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Precautions
Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. Remove all sources of ignition.
6.2 Environmental precautions
Do not allow to get into surface water, drains and ground water.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up
Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal.
Handling and storage
7.1 Precautions for safe handling
Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion
Dust may form explosive mixture in air. Keep away from heat and sources of ignition.
Hygiene measures
Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands before breaks and immediately after handling the product. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Suitable materials
LDPE (low density polyethylene), Polypropylene-foil (PP)
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CLOTHIANIDIN)
- Chemical name:
- (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Packaging: 9, E1
Bulk: 9, E1
Haz ID: 90
EAC: 2Z
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CLOTHIANIDIN)
- Chemical name:
- (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Packaging: 9, E1
Bulk: 9, E1
Haz ID: 90
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CLOTHIANIDIN)
- Chemical name:
- (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- EmS code:
- F-A
- S-F
- Labels:
- Packaging: 9, P
Bulk: 9, P - Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CLOTHIANIDIN)
- Chemical name:
- (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine
- Language:
- English
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Packaging: 9, E1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
8.1 Control parameters
Components CAS-No. Control parameters Update Basis
Clothianidin 210880-92-5 2,8 mg/m3 (TWA) OES BCS
8.2 Exposure controls
Respiratory protection
If product is handled while not enclosed, and if contact may occur:
Wear respirator with a particle filter mask (protection factor 10) conforming to European Norm EN149FFP2 or EN140P2 or equivalent.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.
Hand protection
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Wash gloves when contaminated. Dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.
| Material | Nitrile rubber |
| Rate of permeability | > 480 min |
| Glove thickness | > 0.4 mm |
| Protective index | Class 6 |
| Directive | Protective gloves complying with EN 374 |
Eye protection
Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection
Wear standard coveralls and Category 3 Type 5 suit.
If there is a risk of significant exposure, consider a higher protective type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.
Stability and reactivity
10.1 Reactivity
Stable under normal conditions.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Capable of deflagration. No hazardous reactions when stored and handled according to prescribed instructions.
10.4 Conditions to avoid
Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Store only in the original container.
10.6 Hazardous decomposition products
No decomposition products expected under normal conditions of use.
Disposal considerations
13.1 Waste treatment methods
Product
In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging
Not completely emptied packagings should be disposed of as hazardous waste.
Waste key for the unused product
02 01 08* agrochemical waste containing hazardous substances
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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