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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
22-23 Jun 1999
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7950 (Vapor Pressure)
GLP compliance:
yes
Type of method:
effusion method: vapour pressure balance
Temp.:
25 °C
Vapour pressure:
0 Pa
Temp.:
20 °C
Vapour pressure:
0 Pa

Vapour pressure is strictly proportional to the measured (at different temperatures) mass differences. The vapour pressure - temperature relationship is given by:

log VP (in Pa) = Slope/T (K) + Intercept

Summary results of 6 runs are given in the table below.

Run

Temp. range (°C)

Slope

SD in slope

Intercept

SD in intercept

Log VP (in Pa at 25 °C)

VP at 25 °C (Pa)

1

155 -165

-8918.070

258.545

18.944

0.597

-10.967

1.079E-11

2

161 -151

- 8030.248

224.984

17.004

0.524

-9.930

1.175E-10

3

152 -165

- 7313.304

238.099

15.071

0.552

-9.458

3.483E-10

4

148 - 165

- 8803.934

181.036

18.600

0.421

-10.928

1.180E-11

5

150 - 165

- 7508.806

149.360

15.578

0.347

-9.607

2.472E-10

6

147 - 161

- 8832.562

143.463

18.745

0.336

-10.879

1.321E-10

Mean

1.248E-10

Description of key information

1.3E-10 Pa at 25 °C

3.8E-11 Pa at 20 °C

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
25 °C

Additional information

The vapour pressure was determined in accordance with OECD 104 and EU Method A.4 (vapour pressure balance).