Registration Dossier

Administrative data

First-aid measures

- Inhalation: Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment.
- Skin Contact: Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.
- Eye Contact: Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention.
- Ingestion: If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101° F (38.3°C), shortness of breath, chest congestion or continued coughing or wheezing.

- Most important symptoms/effects, acute & delayed: If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever. The onset of respiratory symptoms may be delayed for several hours after exposure. Defatting dermatitis signs and symptoms may include a burning sensation and/or a dried/cracked appearance.

- Indication of immediate medical attention and special treatment needed: Treat symptomatically.

Fire-fighting measures

Clear fire area of all non-emergency personnel.

- Extinguishing Media: Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Do not use water in a jet.

- Special hazards arising from substance: Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon monoxide may be evolved if incomplete combustion occurs. Will float and can be reignited on surface water. Flammable vapours may be present even at temperatures below the flash point.

Advice for fire-fighters: Wear full protective clothing and self-contained breathing apparatus. Keep adjacent containers cool by spraying with water.

Accidental release measures

Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see below 'Exposure controls / Personal protection'; for information on disposal see below 'Disposal considerations'. Observe the relevant local and international regulations. Evacuate the area of all non-essential personnel. Ventilate contaminated area thoroughly.

- Personal Precautions, Protective Equipment and Emergency Procedures: Do not breathe fumes, vapour. Do not operate electrical equipment.

- Environmental Precautions: Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area. Use appropriate containment (of product and fire fighting water) to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Attempt to disperse the vapour or to direct its flow to a safe location for example by using fog sprays. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) all equipment.

- Methods and Material for Containment and Clean Up: For small liquid spills (< 1 drum), transfer by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. For large liquid spills (> 1 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. Shovel into a suitable clearly marked container for disposal or reclamation in accordance with local regulations.

- Additional Advice: Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. Local authorities should be advised if significant spillages cannot be contained. Maritime spillages should be dealt with using a Shipboard Oil Pollution Emergency Plan (SOPEP), as required by MARPOL Annex 1 Regulation 26.

Handling and storage

- General Precautions: Avoid breathing vapours or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Air-dry contaminated clothing in a well-ventilated area before laundering. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Prevent spillages. Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Never siphon by mouth. Contaminated leather articles including shoes cannot be decontaminated and should be destroyed to prevent reuse. For comprehensive advice on handling, product transfer, storage and tank cleaning refer to the product supplier. Maintenance and Fuelling Activities: Avoid inhalation of vapours and contact with skin.

- Precautions for Safe Handling: Avoid inhaling vapour and/or mists. Avoid prolonged or repeated contact with skin. When using do not eat or drink. Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Earth all equipment. Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Not expected to be a health hazard when used under normal conditions. The vapour is heavier than air, spreads along the ground and distant ignition is possible.

- Conditions for safe storage, including any incompatibilities: Drum and small container storage: Drums should be stacked to a maximum of 3 high. Use properly labelled and closeable containers. Tank storage: Tanks must be specifically designed for use with this product. Bulk storage tanks should be diked (bunded). Locate tanks away from heat and other sources of ignition. Must be stored in a diked (bunded) well-ventilated area, away from sunlight, ignition sources and other sources of heat. The vapour is heavier than air. Beware of accumulation in pits and confined spaces.
Keep in a bunded area with a sealed (low permeability) floor, to provide containment against spillage. Prevent ingress of water.
Additional Information: Ensure that all local regulations regarding handling and storage facilities are followed [fire hazard classification: B; storage class: 3B]
Product Transfer: Avoid splash filling. Wait 2 minutes after tank filling (for tanks such as those on road tanker vehicles) before opening hatches or manholes. Wait 30 minutes after tank filling (for large storage tanks) before opening hatches or manholes. Keep containers closed when not in use. Do not use compressed air for filling, discharging or handling. Contamination resulting from product transfer may give rise to light hydrocarbon vapour in the headspace of tanks that have previously contained gasoline. This vapour may explode if there is a source of ignition. Partly filled containers present a greater hazard than those that are full, therefore handling, transfer and sampling activities need special care.
Recommended Materials: For containers, or container linings use mild steel, stainless steel. Aluminium may also be used for applications where it does not present an unnecessary fire hazard. Examples of suitable materials are: high density polyethylene (HDPE) and Viton (FKM), which have been specifically tested for compatibility with this product. For container linings, use amine-adduct cured epoxy paint. For seals and gaskets use: graphite, PTFE, Viton A, Viton B.
Unsuitable Materials: Some synthetic materials may be unsuitable for containers or container linings depending on the material specification and intended use. Examples of materials to avoid are: natural rubber (NR), nitrile rubber (NBR), ethylene propylene rubber (EPDM), polymethyl methacrylate (PMMA), polystyrene, polyvinyl chloride (PVC), polyisobutylene. However, some may be suitable for glove materials.
Container Advice: Containers, even those that have been emptied, can contain explosive vapours. Do not cut, drill, grind, weld or perform similar operations on or near containers.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

CONTROL PARAMETERS:
- Occupational Exposure Limits: None established.
- Additional Information: In the absence of a national exposure limit, the American Conference of Governmental Industrial Hygienists (ACGIH) recommends the following values for Diesel Fuel: TWA - 100 mg/m3 Critical effects based on Skin and Irritation.
- Derived No Effect Levels (DNEL): No DNEL value has been established.
- PNEC related information: Substance is a hydrocarbon with a complex, unknown or variable composition. Conventional methods of deriving PNECs are not appropriate and it is not possible to identify a single representative PNEC for such substances.

EXPOSURE CONTROLS
- General Information: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Use sealed systems as far as possible. Adequate ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Eye washes and showers for emergency use.
- Occupational Exposure Controls:
1) Personal Protective Equipment: Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers.
2) Eye Protection: Chemical splash goggles (chemical monogoggles). Approved to EU Standard EN166.
3) Hand Protection: Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Select gloves tested to a relevant standard (e.g. Europe EN374, US F739). When prolonged or frequent repeated contact occurs, Nitrile gloves may be suitable. (Breakthrough time of > 240 minutes.) For incidental contact/splash protection Neoprene, PVC gloves may be suitable.
4) Respiratory Protection: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. All respiratory protection equipment and use must be in accordance with local regulations.

- Thermal Hazards: Not applicable.
- Monitoring Methods: Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate.
- Environmental exposure control measures: Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour.
- Exposure Control Measures for Consumers: If repeated and/or prolonged skin exposure to the substance is likely, then wear suitable gloves tested to EN374 and provide employee skin care programmes. Do not ingest. If swallowed then seek immediate medical assistance.

Stability and reactivity

- Reactivity: Stable under normal conditions of use.
- Chemical Stability: Stable under normal conditions of use.
- Possibility of Hazardous Reactions: Reacts with strong oxidising agents.
- Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources.
- Incompatible Materials: Strong oxidising agents.
- Hazardous Decomposition Products: Hazardous decomposition products are not expected to form during normal storage.
Thermal decomposition is highly dependent on conditions. A complex mixture of airborne solids, liquids and gases, including carbon monoxide, carbon dioxide and other organic compounds will be evolved when this material undergoes combustion or thermal or oxidative degradation.

Disposal considerations

- Material Disposal: Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Do not dispose of tank water bottoms by allowing them to drain into the ground. This will result in soil and groundwater contamination. Waste arising from a spillage or tank cleaning should be disposed of in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand.

- Container Disposal: Send to drum recoverer or metal reclaimer. Drain container thoroughly. After draining, vent in a safe place away from sparks and fire. Residues may cause an explosion hazard if heated above the flash point. Do not puncture, cut or weld uncleaned drums. Do not pollute the soil, water or environment with the waste container. Comply with any local recovery or waste disposal regulations.

- Local Legislation: EU Waste Disposal Code (EWC): 13 07 01 fuel oil and diesel. The number given to waste is associated with the appropriate usage. The user must decide if their particular use results in another waste code being assigned.
Disposal should be in accordance with applicable regional, national, and local laws and regulations. Local regulations may be more stringent than regional or national requirements and must be complied with.