Registration Dossier
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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 205-286-2 | CAS number: 137-26-8
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Description of first aid measures
General advice: Show this safety data sheet to the doctor in attendance. Consult a physician.
If inhaled: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical advice/ attention.
In case of skin contact: Wash off immediately with plenty of water for at least 15 minutes. Take off all contaminated clothing immediately. Call a physician or poison control centre immediately.
In case of eye contact: Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/ attention.
If swallowed: Call a physician or poison control centre immediately. Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Symptoms: Irregular cardiac activity, Dermatitis, Eczema, Headache, Nausea, Shortness of breath. May produce an allergic reaction. Health injuries may be delayed.
More severe effects if alcohol is consumed.
Indication of any immediate medical attention and special treatment needed
Treatment: General advice for dithiocarbamates. Biomonitoring possible at chronical exposure: determination of TTCA in the urine at the end of the workday/week. Bloodtesting for delayed effects: livertests, kidney function, thyroid function.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Use water spray to extinguish. Carbon dioxide (CO2), Alcohol-resistant foam
Unsuitable extinguishing media: Do NOT use water jet.
Special hazards arising from the substance or mixture
Specific hazards during firefighting: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Hazardous combustion products: Carbon monoxide, Nitrogen oxides (NOx), Sulphur oxides
Advice for firefighters
Special protective equipment for firefighters: Wear an approved positive pressure self-contained breathing apparatus in addition to standard fire fighting gear.
Further information: Take precautionary measures against static discharges.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions: Wear appropriate personal protective equipment. Local authorities should be advised if significant spillages cannot be contained.
Environmental precautions: Avoid release to the environment.
Methods and material for containment and cleaning up
Methods for cleaning up: Sweep up or vacuum up spillage and collect in suitable container for disposal. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations.
Handling and storage
Precautions for safe handling
Advice on safe handling: Avoid breathing dust. Do not get on skin or clothing. Do not get in eyes. Do not swallow. Ensure adequate ventilation. Wash thoroughly after handling.
Advice on protection against fire and explosion: Minimize dust generation and accumulation. Keep product and empty container away from heat and sources of ignition.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Keep tightly closed. Keep in a dry, cool and well-ventilated place. Keep away from direct sunlight. Use only explosion proof equipment.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Thiram)
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- 9
Special provisions / remarks
- Special provisions:
- Classification Code : M7
Hazard Identification Number : 90
Tunnel restriction code : (-)
Environmentally hazardous : yes
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Thiram)
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- 9
Special provisions / remarks
- Special provisions:
- Classification Code : M7
Hazard Identification Number : 90
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Thiram)
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- EmS code:
- F-A
- S-F
- Labels:
- 9
- Marine pollutant
Special provisions / remarks
- Special provisions:
- Environmentally hazardous : yes
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.
(Thiram)
- Class or division:
- Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Miscellaneous
Special provisions / remarks
- Special provisions:
- Packing instruction (cargo aircraft) : 956
Packing instruction (LQ) : Y956
Packing instruction (passenger aircraft): 956
Additional transport information
Additional information
- Special provisions / remarks / other:
- Shipping in package sizes of less than 5 L (liquids) or 5 KG (solids) may lead to a non-regulated classification.
Exposure controls / personal protection
Control parameters
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name | End Use | Exposure routes | Potential health ef | Value |
| Workers | Dermal | Acute effects | 10 mg/kg |
| Workers | Inhalation | Acute effects | 0.564 mg/m3 |
| Workers | Dermal | Long-term systemic | 1.6 mg/kg |
| Workers | Inhalation | Long-term systemic | 0.118 mg/m3 |
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name | Environmental Compartment | Value |
| Fresh water | 0.00046 mg/l |
| Fresh water sediment | 0.047 mg/kg |
| Marine water | 0.000046 mg/l |
| Marine sediment | 0.0047 mg/kg |
| Soil | 0.00912 mg/kg |
| Sewage treatment plant | 0.0311 mg/l |
Exposure controls
Engineering measures
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Personal protective equipment
Eye protection: Wear safety glasses with side shields (or goggles). Face-shield Always wear eye protection when the potential for inadvertent eye contact with the product cannot be excluded.
Hand protection remarks: Rubber gloves Neoprene gloves The data about break through time/strength of material are standard values! The exact break through time/strength of material has to be ob tained from the producer of the protective glove.
Skin and body protection: Complete suit protecting against chemicals.
Respiratory protection: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Effective dust mask.
Protective measures: Remove respiratory and skin/eye protection only after vapours have been cleared from the area. Ensure that eye flushing systems and safety showers are located close to the working place. Use personal protective equipment as required.
Stability and reactivity
Reactivity: None reasonably foreseeable.
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions
Hazardous reactions: Hazardous decomposition products formed under fire conditions. Dust can form an explosive mixture in air.
Conditions to avoid: Avoid dust formation. Heat, flames and sparks.
Incompatible materials
Materials to avoid: Strong oxidizing agents Strong acids
Hazardous decomposition products
Carbon monoxide
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Sulphur oxides
Disposal considerations
Waste treatment methods
Product: Dispose of in accordance with local regulations.
Contaminated packaging:
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.