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Guidance on Safe Use

First-aid measures

First-aid measures general : In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
In a life threatening condition soon carry out resuscitation affected and seek medical advice.
Respiratory arrest: immediately administer artificial respiration.
Cardiac arrest: immediately perform indirect heart massage.
Unconsciousness: place patient in recovery position.
First-aid measures after inhalation : Interrupt exposure source immediately and remove victim to fresh air. Remove contaminated clothing, protect the victim against cold. Get medical attention, especially if
persists cough, breathlessness or other symptoms.
First-aid measures after skin contact : Take off contaminated clothing, wash the area with plenty of lukewarm water, if there was no injury to the skin, it is possible to use soap, soap or shampoo, get medical attention, especially if persists skin irritation.
First-aid measures after eye contact : Immediately flush eyes with running water, open the eyelids (even violence); If a victim has contact lenses, remove them immediately, rinse for at least 10 minutes and get medical, professional treatment if possible.
First-aid measures after ingestion : DO NOT INDUCE VOMITING - alone induced vomiting can cause complications. If possible, give activated charcoal in an amount of 5 crushed tablets, obtain medical attention.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Foam. Dry chemical. Water spray.
Unsuitable extinguishing media : Strong water jet.

5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire : Thermal decomposition giving toxic and corrosive products : Hydrogen chloride gas,Phosgene, Carbon oxides.

 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Self-contained breathing apparatus.

 

Accidental release measures

 Personal precautions, protective equipment and emergency procedures
 For non-emergency personnel Protective equipment : Protective clothing including eye, respiratory passages and hand protection.
For emergency responders
No additional information available

Handling and storage

1. Precautions for safe handling
Precautions for safe handling : Observe working instructions. Provide local exhaust or general room ventilation.
Hygiene measures: Always wash hands after handling the product. Do not eat, drink or smoke when using this product.
2. Conditions for safe storage, including any incompatibilities
Technical measures : Store the product under a nitrogen (or inert) atmosphere.
Storage conditions : Store away from sources of heat and ignition, separated from other substances, preferably in the original containers kept tightly closed. Storerooms should be provided with a first aid
box and a drinking water supply station. Prevent unauthorised access. Provide storage tanks with containment basins of standardised content.
Incompatible products : Store separate from: Alkalis, Alkali metals, Alkaline earth, Water.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3082

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID , N.O.S. (1,1,3,3 -
tetrachloroprop-1-ene)

Chemical name:

1,1,3,3-Tetrachloroprop-1-ene

Language:

English

Packing group:

Packing group III: Substances presenting low danger

Labels:

6.1

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3082

Shipping

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

EmS code:

F-A

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3082

Shipping

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Remarks

SpecialProvisions

Exposure controls / personal protection

Personal protective equipment:
Gloves. Protective clothing. Protective goggles. Gas mask.
Personal protective equipment symbol(s):

Eye and face protection
Eye protection:Protective goggles or face shield
Skin protection
Skin and body protection:
Wear suitable protective clothing
Hand protection:
Chemical resistant gloves (according to European standard EN 374 or equivalent)
 Respiratory protection
Respiratory protection: Respirator
Thermal hazards
No additional information available

Stability and reactivity

Chemical stability
Slightly unstable in water under cold conditions resulting in low pH, very unstable in water under hot conditions. Unstable in contact with alkaline –
explosion hazard!.
Possibility of hazardous reactions
Risk of explosion in contact with alkalis.
Conditions to avoid
Elevated temperature. Do not store in direct sunlight. Strictly avoid contact with alkali - explosion hazard!.
Incompatible materials
Store separate from: Alkalis, Alkali metals, Alkaline earth, Water.
Hazardous decomposition products
Thermal decomposition giving toxic and corrosive products : Hydrogen chloride gas, Phosgene, Carbon oxides.

Disposal considerations

Waste treatment methods
Regional legislation (waste) : Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives. Act no. 185/2001 Coll, on waste and amendment of some other acts, as amended.
Product/Packaging disposal recommendations : Empty containers should be taken for recycling, recovery or waste in accordance with local regulation.
European List of Waste (LoW) code : 07 07 03* - organic halogenated solvents, washing liquids and mother liquors