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Physical & Chemical properties

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Link to relevant study record(s)

Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From 12 October 2017 to 21 February 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to other study
Reason / purpose for cross-reference:
reference to other study
Reason / purpose for cross-reference:
reference to other study
Reason / purpose for cross-reference:
reference to other study
Qualifier:
according to guideline
Guideline:
other: UN Manual of Tests and Criteria: Test N.4 (Test method for Self-Heating Substances)
Version / remarks:
2015
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Remarks on result:
other: no spontaneous ignition occured at 140°C

No spontaneous ignition occurred and no exothermic effect of the test item was observed at 140°C. It demonstrated that 1,3-Bis (4-hydroxy benzoyl) benzene

is “not a self-heating substance”. According to the UN guideline, no further testing is required.

After the experiment, the consistency of the sample was unchanged, therefore it was concluded that no reaction and/or decomposition of the test item was observed.

Conclusions:
The test item is not classified as "self-heating" according to GHS criteria, based on the negative results obtained at 140°C using a 10 cm sample cube.
Executive summary:

The self-heating temperature of the test item was determined (Brekelmans, 2018) according to a recognised guideline and in compliance with GLP. No deviation from the guideline was observed during the test.

A sample of the test item was maintained at 140°C in a sample cube of 10 cm inside an oven during 24 hours.

No spontaneous ignition occurred and no exothermic effect of the test item was observed at 140°C. According to the guideline no further test was required and the test item is not classified as "self-heating" according to GHS criteria.

Description of key information

The self-heating properties of test item were detemined in a key study of Klimisch validity 1 performed according to recognised guidelines and in compliance with GLP (Brekelmans, 2018).

No deviation from the guideline was observed in the study.

Key value for chemical safety assessment

Additional information

Based on the experimental results obtained in the key study (Brekelmans, 2018), the test item is not classified for self-heating hazard according to UN GHS criteria.