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Guidance on Safe Use

First-aid measures

Eye Contact:

Rinse immediately with plenty of water for at least 15 minutes. Hold eyelid(s) open during rinsing. Obtain medical advice if there are persistent symptoms.

Skin Contact:

Flush with a continuous flow of lukewarm water for 20 minutes or until material is removed. Wash with plenty of water and soap. Remove contaminated clothing and shoes without delay. Obtain medical attention if symptoms persist. Do not reuse contaminated clothing without laundering. Destroy or thoroughly clean shoes before reuse.

Ingestion:

If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.

Inhalation:

Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms.

Fire-fighting measures

Extinguishing Media:

Suitable Extinguishing Media: Use water spray or fog, carbon dioxide or dry chemical.

Unsuitable Extinguishing Media: full water jet.

Special Hazards Arising from the Substance or Mixture: Keep containers cool by spraying with water if exposed to fire.

Advice for Firefighters:

Protective Equipment: Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing.

Accidental release measures

Personal Precautions, Protective Equipment and Emergency Procedures:

Where exposure level is not known, wear approved, positive pressure, self-contained respirator. Where exposure level is known, wear approved respirator suitable for level of exposure. In addition to the protective clothing/equipment, wear impermeable boots.

Environmental Precautions:

None known

Methods and Material for Containment and Cleaning Up:

Cover spills with some inert absorbent material; sweep up and place in a waste disposal container. Flush spill area with water.

Handling and storage

Precautions for Safe Handling:

Precautions: Wash hands thoroughly after handling. Wear protective gloves and eye/face protection.

Special Handling Statements: Provide good ventilation of working area (local exhaust ventilation if necessary).

Avoid excessive heat, contamination or exposure to direct sunlight to prevent polymerization.

Conditions for Safe Storage, including any incompatibilities:

Store in a cool, dry, well ventilated place and keep container tightly closed. Keep away from heat sources and direct sunlight.

Storage Temperature: Store at 4 - 40°C

Reason: Quality.

Storage Class (TRGS 510): 10

Specific End Uses:

Refer to the exposure scenarios if applicable.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

Not applicable/Not regulated

Shipping

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

Not applicable/Not regulated

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

Not applicable/Not regulated

Shipping

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

Not applicable/Not regulated

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

Engineering Measures:

Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure.

Respiratory Protection:

For operations where inhalation exposure can occur use an approved respirator. Recommendations are listed below. Other protective respiratory equipment may be used based on user's own risk assessment.

Recommended: Full Face Mask with organic vapor cartridge, Type A filter (BP >65°C)

Eye protection:

Wear eye/face protection such as chemical splash proof goggles or face shield. Eyewash equipment and safety shower should be provided in areas of potential exposure.

Skin Protection:

Avoid skin contact. Wear impermeable gloves and suitable protective clothing.

Hand protection:

Wear protective gloves. Recommendations are listed below. Other protective materials may be used based on user's own risk assessment. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Replace gloves immediately when torn or any change in appearance (dimension, color, flexibility etc.) is noticed.

Gloves for repeated or prolonged exposure - non exhaustive list: Nitrile rubber (NBR), thickness: > 0.56 mm, break through time: up to 480 m

Gloves for short term exposure/splash protection - non exhaustive list: Nitrile rubber (NBR), thickness: 0.1 mm, break through time: up to 30 min

The chemical resistance depends on the type of product and amount of product on the glove. Therefore gloves need to be changed when in contact with chemicals.

Not suitable gloves - non exhaustive list: Latex gloves

Due to many conditions (e.g. temperature, abrasion) the practical usage of a chemical protective glove in practice may be much shorter than the permeation time determined through testing. Use PE gloves as under gloves for difficult situations like for instance: high exposure, unknown composition or unknown properties of the chemicals.

Additional Advice:

Food, beverages, and tobacco products should not be carried, stored, or consumed where this material is in use. Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water. It is recommended that a shower be taken after completion of workshift especially if significant contact has occurred. Work clothing should then be laundered prior to reuse. Street clothing should be stored separately from work clothing and protective equipment. Work clothing and shoes should not be taken home.

Stability and reactivity

Reactivity: No information available

Chemical Stability: Stable

Possibility of Hazardous Reactions:

Polymerization: May occur

Conditions To Avoid: Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers

Hazardous polymerization can occur when exposed to direct sunlight. Hazardous exothermic polymerization can occur when heated. Avoid contact with bases or

amines. Avoid contact with strong oxidizing agents. Avoid contact with free radical initiators.

Conditions to avoid: Avoid direct exposure to sunlight. Avoid temperatures above 60°C (140°F). Avoid friction with temperature increase as result. Avoid exposure to strong UV sources.

Avoid direct contact with heat sources.

Incompatible Materials: Avoid contact with peroxides, Copper, copper alloys, carbon steel, iron and rust. Avoid free radical producing initiators, contact with alkalis. They give an

exothermic reaction with the product. Unintentional contact with them should be avoided. Avoid contact with active metals.

Hazardous Decomposition Products:

Carbon dioxide, carbon monoxide (CO), hydrogen cyanide (HCN), nitrogen oxides (NOx)

Disposal considerations

Waste Treatment Methods:

The company encourages the recycle and reuse of products and packaging, where possible and permitted.

Product disposal:

When recycle or reuse is not possible, the comany recommends that our products, especially when classified as hazardous, be disposed of by thermal treatment or incineration at approved facilities. All local and national regulations should be followed. For disposal within the European Community, waste codes according to Directive 2008/98/EC should be assigned by the user based on the application for which the product was used.

Packaging disposal:

Handle contaminated packages in the same way as the product itself. Disposal of emptied and cleaned packaging must be made in accordance with applicable local and national regulations.

Disposal-relevant information:

Do not release directly or indirectly to surface water, ground water, soil or public sewage system.