Registration Dossier
Registration Dossier
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EC number: 203-891-6 | CAS number: 111-64-8
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and
transport in stable sideways position (recovery position). First aid personnel should pay attention to
their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye
specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, induce vomiting, seek medical attention.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
dry powder, carbon dioxide, foam
Unsuitable extinguishing media for safety reasons:
water
Special hazards arising from the substance or mixture
hydrogen chloride, carbon oxides, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not empty into drains.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of absorbed material in accordance with regulations.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Protect against moisture.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated
place.
Storage stability:
Storage duration: 6 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with workplace control parameters
112-13-0: Decanoyl chloride
75-44-5: carbonyl chloride
TWA value 0.08 mg/m3 ; 0.02 ppm (OEL (EU))
STEL value 0.4 mg/m3 ; 0.1 ppm (OEL (EU))
PNEC
freshwater: 0.144 mg/l
marine water: 0.0144 mg/l
intermittent release: 1.44 mg/l
STP: 100 mg/l
sediment (freshwater): 1.02 mg/kg
soil: 0.275 mg/kg
DNEL
No DNEL value available.
Exposure controls
Personal protective equipment
Respiratory protection:
Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
nitrile rubber (NBR) - 0.4 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures
Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Handle in accordance
with good industrial hygiene and safety practice.
Stability and reactivity
Reactivity
Corrosion to metals: Corrosive effect on metals.
Reactions with
water/air:
Reaction with: water
Flammable gases: no
Toxic gases: yes
Which toxic gases: hydrogen chloride (HCl)
Corrosive gases: yes
Which corrosive gases: hydrogen chloride (HCl)
Smoke or fog: yes
Type of smoke or fog: Hydrochloric acid
Peroxides:
Which Peroxides:
Formation of
flammable gases:
Remarks: Forms no flammable gases in the
presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Evolution of corrosive gases/vapours. Reacts with water and basic components to generate heat. On
contact with water, gaseous decomposition products are formed, which cause build-up of pressure in
tightly closed containers. Reacts with alkalies and metals. Reacts with alcohols, amines, aqueous
acids and alkalies. Reacts with water and moisture, with formation of hydrogen chloride. Partly very
violent reactions with bases and numerous organic classes of substances such as alcohols and
amines. Addition of water leads to increase in temperature. In damp air hydrochloric acid formation is
possible. Violent reactions with water and/or alcohols, with formation of hydrochloric acid.
Conditions to avoid
Avoid electro-static charge. Avoid humidity. Avoid heat. Avoid prolonged storage. Disregard of the
conditions mentioned may result in undesirable decomposition reactions.
Incompatible materials
Substances to avoid:
water, bases, amines, alkaline reactive substances, alcohols
Hazardous decomposition products
Hazardous decomposition products:
hydrogen chloride
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling
after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
