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EC number: 235-741-0 | CAS number: 12645-31-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Auto flammability
Administrative data
Link to relevant study record(s)
- Endpoint:
- auto-flammability
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- Testing was conducted between 23 May 2011 and 23 June 2011.
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: see 'Remark'
- Remarks:
- Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: Testing was conducted using a procedure designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Auto-ignition temperature:
- 260 °C
- Atm. press.:
- > 101.63 - 102.19 kPa
- Remarks on result:
- other:
- Relative self-ignition temperature:
- 260 °C
- Remarks on result:
- other:
- Remarks:
- at atm. press. of >101.63 - 102.19 kPa
- Conclusions:
- The test item has been determined to have an auto-ignition temperature of 260 ± 5°C.
- Executive summary:
Method
The auto-ignition temperature was determined by heating aliquots of the test item in a flask and observing for any ignition. Testing was conducted using a procedure designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
Results
Test Temperature (ºC)
Test Volume (µl)
Ignition Delay (s)
Observations
200(clean flask)
70
>300
No ignition.
250(clean flask)
70
>300
No ignition.
300(clean flask)
70
10
A yellow flame.
280
70
>300
No ignition.
290
70
14
A yellow flame.
286
70
>300
No ignition.
288
70
13
A yellow flame.
286(clean flask)
70
>300
No ignition.
286(clean flask)
200
19
A yellow flame. Grey fumes were emitted.
284(clean flask)
200
18
A yellow flame. Grey fumes were emitted.
282(clean flask)
200
21
A yellow flame. Grey fumes were emitted.
280(clean flask)
200
23
A yellow flame. Grey fumes were emitted.
276(clean flask)
200
38
A yellow flame. Grey fumes were emitted.
274(clean flask)
200
33
A yellow flame. Grey fumes were emitted.
270(clean flask)
200
46
A yellow flame. Grey fumes were emitted.
268(clean flask)
200
34
A yellow flame. Grey fumes were emitted.
264
200
40
A yellow flame. Grey fumes were emitted.
262
200
33
A yellow flame. Grey fumes were emitted.
258
200
>300
No ignition. Grey fumes were emitted.
260(clean flask)
200
>300
No ignition. Grey fumes were emitted.
260(clean flask)
400
70
A yellow flame. Grey fumes were emitted.
258(clean flask)
400
>300
No ignition. Grey fumes were emitted.
258(clean flask)
600
>300
No ignition. Grey fumes were emitted.
258(clean flask)
800
>300
No ignition. Grey fumes were emitted.
258(clean flask)
1000
>300
No ignition. Grey fumes were emitted.
258(clean flask)
1200
>300
No ignition. Grey fumes were emitted.
Room temperature:20°C
Atmospheric pressure: 101.63 to 102.19 kPaConclusion
The test item has been determined to have an auto-ignition temperature of 260 ± 5°C.
- Endpoint:
- auto-flammability
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2013
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Although this study was conducted in accordance with international guidelines, it was not conducted according to the principles of GLP.
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- GLP compliance:
- no
- Auto-ignition temperature:
- 250 °C
- Atm. press.:
- 1 016 hPa
- Remarks on result:
- other:
- Conclusions:
- The auto ignition temperature of the substance is 250°C
- Executive summary:
The first principal test will not be used for the assessment because the lowest auto-ignition temperature deviates more than 10 K from the lowest auto-ignition temperature in the other principal tests. The lowest auto-ignition temperature of the test item was determined to be 252 °C in the main test. Due to safety reasons and according to the guidelines the lowest measured temperature at which an ignition was observed was rounded to the next lower number divisible by 5, giving a value of 250 °C.
Referenceopen allclose all
Results
Test Temperature (ºC) | Test Volume (µl) | Ignition Delay (s) | Observations |
200(clean flask) | 70 | >300 | No ignition. |
250(clean flask) | 70 | >300 | No ignition. |
300(clean flask) | 70 | 10 | A yellow flame. |
280 | 70 | >300 | No ignition. |
290 | 70 | 14 | A yellow flame. |
286 | 70 | >300 | No ignition. |
288 | 70 | 13 | A yellow flame. |
286(clean flask) | 70 | >300 | No ignition. |
286(clean flask) | 200 | 19 | A yellow flame. Grey fumes were emitted. |
284(clean flask) | 200 | 18 | A yellow flame. Grey fumes were emitted. |
282(clean flask) | 200 | 21 | A yellow flame. Grey fumes were emitted. |
280(clean flask) | 200 | 23 | A yellow flame. Grey fumes were emitted. |
276(clean flask) | 200 | 38 | A yellow flame. Grey fumes were emitted. |
274(clean flask) | 200 | 33 | A yellow flame. Grey fumes were emitted. |
270(clean flask) | 200 | 46 | A yellow flame. Grey fumes were emitted. |
268(clean flask) | 200 | 34 | A yellow flame. Grey fumes were emitted. |
264 | 200 | 40 | A yellow flame. Grey fumes were emitted. |
262 | 200 | 33 | A yellow flame. Grey fumes were emitted. |
258 | 200 | >300 | No ignition. Grey fumes were emitted. |
260(clean flask) | 200 | >300 | No ignition. Grey fumes were emitted. |
260(clean flask) | 400 | 70 | A yellow flame. Grey fumes were emitted. |
258(clean flask) | 400 | >300 | No ignition. Grey fumes were emitted. |
258(clean flask) | 600 | >300 | No ignition. Grey fumes were emitted. |
258(clean flask) | 800 | >300 | No ignition. Grey fumes were emitted. |
258(clean flask) | 1000 | >300 | No ignition. Grey fumes were emitted. |
258(clean flask) | 1200 | >300 | No ignition. Grey fumes were emitted. |
Room temperature:20°C
Atmospheric pressure: 101.63 to 102.19 kPa
Preliminary test:The following table shows the results of the preliminary test. Temperatures where self-ignition was detected are marked with +; temperatures where no self-ignition was detected are marked with - in the table below. The amount of test item tested at each measurement is indicated as numbers of drops.
preliminary test | ||
T/°C | drops | + /- |
202 | 5 | - |
252 | 5 | - |
302 | 5 | + |
282 | 5 | + |
262 | 5 | + |
257 | 5 | - |
barometric pressure: 983.0 hPa |
Result of the preliminary test:The lowest self-ignition temperature of the test item was determined to be 262 °C in the preliminary test.
Main test:The following table shows the results of the three principal tests. Temperatures where self-ignition was detected are marked with +; temperatures where no self-ignition was detected are marked with - in the table below. The amount of test item tested at each measurement is indicated as numbers of drops.
first principal test | second principal test | ||||
T/°C | drops | + /- | T/°C | drops | + /- |
263 | 6 | + | 262 | 6 | + |
257 | 6 | - | 257 | 10 | + |
257 | 8 | - | 253 | 10 | + |
257 | 3 | - | 248 | 12 | - |
257 | 2 | - | 248 | 10 | - |
257 | 5 | - | 248 | 8 | - |
257 | 10 | - | 248 | 3 | - |
257 | 1 | - | 248 | 5 | - |
257 | 7 |
| 248 | 1 | - |
257 | 9 | - | 248 | 6 | - |
257 | 4 | - | 248 | 9 | - |
257 | 6 | - | 248 | 4 | - |
barometric pressure: 1010.1 hPa | barometric pressure: 1009.4 hPa |
3rdprincipal test | 4thprincipal test | ||||
T /°C | drops | + /- | T /°C | drops | + /- |
252 | 10 | + | 257 | 10 | + |
247 | 10 | - | 252 | 10 | - |
248 | 5 | - | 252 | 6 | - |
247 | 1 | - | 252 | 13 | - |
248 | 12 | - | 252 | 8 | - |
248 | 8 | - | 252 | 9 | - |
248 | 3 | - | 252 | 3 | - |
247 | 7 | - | 252 | 1 | - |
247 | 4 | - | 252 | 5 | - |
247 | 9 | - | 252 | 7 | - |
248 | 2 | - | 252 | 2 | - |
248 | 6 | - | 252 | 4 | - |
barometric pressure: 1015.6 hPa | barometric pressure: 1023.2 hPa |
Result of the main test:The first principal test will not be used for the assessment because the lowest auto-ignition temperature deviates more than 10 K from the lowest auto-ignition temperature in the other principal tests. The lowest auto-ignition temperature of the test item was determined to be 252 °C in the main test. Due to safety reasons and according to the guidelines the lowest measured temperature at which an ignition was observed was rounded to the next lower number divisible by 5, giving a value of 250 °C.
Description of key information
Auto-ignition temperature = 260 ± 5°C (102.2 kPa); Tremain & Atwal (2011); EU Method A.15.
Auto-ignition temperature = 250°C (101.6 kPa); Krack (2013); EU Method A.15.
Key value for chemical safety assessment
- Autoflammability / Self-ignition temperature at 101 325 Pa:
- 260 °C
Additional information
The overall endpoint determination for auto-ignition temperature was conducted by heating aliquots of the test item in a flask and observing for any ignition. Testing was conducted using a procedure designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
The test item has been determined to have an auto-ignition temperature of 260 ± 5°C.
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