N-nitro-N-(3-methyl-3,6-dihydro-2H-1,3,5-oxadiazin-4-yl)amine

Oxidising properties

Administrative data

Endpoint:

oxidising solids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

1995-09-04 until 1995-11-27

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: Guideline-conform study under GLP without deviations.

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

1995

Report date:

1995

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.17 (Oxidising Properties (Solids))

Deviations:

no

GLP compliance:

yes

Remarks:

This study was performed in compliance with Good Laboratory Practice (GLP) in Switzerland, Procedures and Principles, March 1986.

Test material

Test material information

Constituent 1

Reference substance name:

-

EC Number:

431-060-1

EC Name:

-

Cas Number:

153719-38-1

Molecular formula:

Hill formula: C4H8N4O3 CAS formula: C4H8N4O3

IUPAC Name:

3-methyl-N-nitro-3,6-dihydro-2H-1,3,5-oxadiazin-4-amine

Details on test material:

- Name of test material (as cited in study report): CA 2343 A (Intermediate of CGA 293343)
- Substance type: mono-constituent organic substance
- Physical state: solid, fine, white powder
- Analytical purity: 96.7 %
- Impurities (identity and concentrations): no data
- Purity test date: no data
- Lot/batch No.: P.503005
- Expiration date of the lot/batch: Date of reanalysis: December 1996
- Stability under test conditions: not reported
- Storage condition of test material: 0 - 5 °C

Study design

Contact with:

powdered cellulose

Results and discussion

Test results (Oxidising solids)

Test results (Oxidising solids) 1

Sample tested:

test mixture (not specified)

Remarks:

migrated information

Parameter:

maximum burning rate

Result:

5 other: mm/s (migrated information)

Remarks on result:

other: Max. burning rate: mixture with 70% of test substance / 30% cellulose powder; result as average of six test runs; reaction described as "steady burning with flame throughout the whole mass".

Test results (Oxidising solids) 2

Sample tested:

reference mixture (not specified)

Remarks:

migrated information

Parameter:

maximum burning rate

Result:

4.4 other: mm/s (migrated information)

Remarks on result:

other: Reference substance was mixture of 60% Barium Nitrate with 40% Cellulose; reaction described as "steady burning with flame throughout the whole mass".

Test results (Oxidising solids) 3

Sample tested:

test mixture (not specified)

Remarks:

migrated information

Parameter:

maximum burning rate

Result:

5.3 other: mm/s (migrated information)

Remarks on result:

other: Max. burning rate: mixture with 70% of test substance / 30% Kieselgur; result as average of six test runs; reaction described as "steady burning with flame throughout the whole mass".

Any other information on results incl. tables

1. Test run of test substance in mixture with combustible substance cellulose powder:

Max. burning rate of test substance mixture / Max. burning rate of reference substance mixture = 5.0 / 4.4 = 1.14

2. Test run of test substance in mixture with inert substance Kieselgur:

(Max. burning rate test substance/Kieselgur) / (Max. burning rate test substance/Cellulose) = 5.3 / 5.0 = 1.06

Since there was no significant difference between the test results obtained by mixing the test substance with combustible material and inert material, the test item is considered not being an oxidizing substance.

Applicant's summary and conclusion

Interpretation of results:

other: no oxidising properties

Remarks:

Migrated information

Conclusions:

Since there was no significant difference between the test results obtained by mixing the test substance with combustible material and inert material, the test item is considered not being an oxidizing substance.

Executive summary:

The purpose of this study was to evaluate the oxidizing properties of test substance CA 2343 (oxadiazinamine). The study was conducted according to Directive 92/69/EEC, Part. A.17. A certain increase of the burning of a mixture containing test subtance and cellulose powder 30%:70% compared to the reference mixture was observed, However, since there was no significant difference between the test results obtained by mixing the test substance with combustible material (cellulose) and inert material (Kieselgur), the test item is considered not being an oxidizing substance.