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Physical & Chemical properties

Flash point

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2021-04-20
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
European Commission Regulation (EC) No. 440/2008
Deviations:
no
GLP compliance:
no
Type of method:
closed cup
Flash point apparatus:
other: Rapid-Tester according to rapid equilibrium closed cup method
Key result
Flash point:
36 °C
Atm. press.:
1 013 hPa

The following tables show the results of the measurements as temperatures where ignition (+) was detected and where not (-).


Table 1 and Table 2 show the results from the flash point measurements


 


Table 1: Preliminary test






























Test item / mL



Starting temperature / °C



Ignition temperature / °C



Ignition + / -



2



20



39.0



+



2



20



41.5



+



2



19



37.0



+



 


Table 2: Main test














































































Test item / mL



Temperature / °C



Ignition + / -



Barometric pressure / hPa



2



37.0



+



1013.4



2



32.0



-



2



33.0



-



2



34.0



-



2



35.0



-



2



36.0



-



2



37.0



+



2



36.5



+



2



36.0



-



2



36.5



+



2



36.0



-



2



36.5



+



2



36.0



-



 


The lowest flash point corrected to 1013 hPa was rounded down with an accuracy of 0.5 °C giving a value of 36.0 °C.

Interpretation of results:
Category 3 (flammable liquids) based on GHS criteria
Conclusions:
The flashpoint of the test item was determined to be 36.0 °C under atmospheric conditions (1013 hPa).
Executive summary:

The flash point was determined according to EU method A.9 in a closed cup experiment according to rapid equilibrium method. The test item was filled into the test vessel and the flash point was determined with temperature steps of 0.5 K. For each temperature step a fresh sample was used. The main test was performed at constant temperature and equilibrium conditions. The final flash point rounded down with an accuracy of 0.5 K was determined to be 36.0 °C.

Description of key information

The flashpoint of the test item was determined to be 36.0 °C under atmospheric conditions (1013 hPa) (reference 4.11-1).

Key value for chemical safety assessment

Flash point at 101 325 Pa:
36 °C

Additional information

The flash point was determined according to EU method A.9 in a closed cup experiment according to rapid equilibrium method. The test item was filled into the test vessel and the flash point is determined with temperature steps of 0.5 K. For each temperature step a fresh sample was used. The main test was performed at constant temperature and equilibrium conditions. The final flash point rounded down with an accuracy of 0.5 K was determined to be 36.0 °C.


 


Classification, Labelling, and Packaging Regulation (EC) No 1272/2008
The available experimental test data are reliable and suitable for classification purposes under Regulation (EC) No 1272/2008. Based on available data from flash point determiniation the test item is considered to be a flammable liquid (Category 3, H226: Flammable liquid and vapour).