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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
other: UN Manual of Tests and Criteria, 7th rev. edition, New York and Geneva, 2019: Part III, Section 33, Test N.4 Test method for self-heating substances (UN) and Appendix 6 Screening Procedures, A6.5.3.2 (a) Grewer Oven test
Qualifier:
according to guideline
Guideline:
other: VDI guideline 2263, Part 1, 1990: Test Methods for the Determination of the Safety Characteristic of Dusts, 1.4.1 Test according to Grewer
Qualifier:
according to guideline
Guideline:
other: UN Recommendations on the TRANSPORT OF DANGEROUS GOODS, Model Regulations, Vol. I, 21st rev. edition, New York and Geneva, 2019: Class 4, Division 4.2 – Substances liable to spontaneous combustion
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
Batch C000363565
Key result
Relative self-ignition temperature:
> 410 °C
Remarks on result:
preliminary test
Conclusions:
The pure test item Ti3O5/Al2O3 Granulat 0.7-5mm indicated no self-ignition at atmospheric pressure up to a temperature of approx. 410 °C in a Screening test in the Grewer Oven. Due to this Screening test in the Grewer Oven, it can be assumed that the UN Test N.4 at 140 °C is negative.

On the basis to the results of the test on the self-ignition in the Grewer Oven the test item is classified as follows:
UN Transport Regulation: The test item does not have to be classified as self-heating substance in Class 4, Division 4.2 according to the UN Transport Regulation.
GHS / CLP Regulation (EC) No 1272/2008 Annex I: 2.11: The test item does not have to be classified as self-heating substance according to GHS/CLP Regulation (EC) No 1272/2008 Annex I: 2.11.
Executive summary:

The pure test item Ti3O5/Al2O3 Granulat 0.7-5mm indicated no self-ignition at atmospheric pressure up to a temperature of approx. 410 °C in a Screening test in the Grewer Oven. Due to this Screening test in the Grewer Oven, it can be assumed that the UN Test N.4 at 140 °C is negative.

On the basis to the results of the test on the self-ignition in the Grewer Oven the test item is classified as follows:

UN Transport Regulation: The test item does not have to be classified as self-heating substance in Class 4, Division 4.2 according to the UN Transport Regulation.

GHS / CLP Regulation (EC) No 1272/2008 Annex I: 2.11: The test item does not have to be classified as self-heating substance according to GHS/CLP Regulation (EC) No 1272/2008 Annex I: 2.11.

Description of key information

The pure test item Ti3O5/Al2O3 Granulat 0.7-5mm indicated no self-ignition at atmospheric pressure up to a temperature of approx. 410 °C in a Screening test in the Grewer Oven. Due to this Screening test in the Grewer Oven, it can be assumed that the UN Test N.4 at 140 °C is negative.

Key value for chemical safety assessment

Additional information