Registration Dossier
Registration Dossier
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EC number: 432-130-2 | CAS number: 119345-01-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Immediate Medical Assistance Required: No
Inhalation
Remove to fresh air.
Get medical attention.
Remove to fresh air.
In case of irritation of respiratory system or mucous membranes or if feeling unwell or after prolonged exposure get medical attention.
Wear respiratory protection.
Skin contact
Immediately flush skin thoroughly with warm water and soap for at least 15 minutes while removing contaminated clothing and shoes.
Do not use organic solvents.
If symptoms persist, seek medical attention.
If skin irritation occurs: Get medical advice/attention.
Eye contact
Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion
If conscious, make the victim drink the following:
Drink 1 or 2 glasses of water.
Get medical attention immediately.
Give medicinal activated charcoal 10 g in 100 ml water at 20 minute intervals (5 x).
Give small amounts of water to drink.
Do NOT induce vomiting. In case of spontaneous vomiting ensure that vomitus can drain freely to avoid risk of suffocation.
In case of unconsciousness or convulsion no oral administration.
Inhalation
Remove to fresh air.
Get medical attention.
Remove to fresh air.
In case of irritation of respiratory system or mucous membranes or if feeling unwell or after prolonged exposure get medical attention.
Wear respiratory protection.
Skin contact
Immediately flush skin thoroughly with warm water and soap for at least 15 minutes while removing contaminated clothing and shoes.
Do not use organic solvents.
If symptoms persist, seek medical attention.
If skin irritation occurs: Get medical advice/attention.
Eye contact
Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion
If conscious, make the victim drink the following:
Drink 1 or 2 glasses of water.
Get medical attention immediately.
Give medicinal activated charcoal 10 g in 100 ml water at 20 minute intervals (5 x).
Give small amounts of water to drink.
Do NOT induce vomiting. In case of spontaneous vomiting ensure that vomitus can drain freely to avoid risk of suffocation.
In case of unconsciousness or convulsion no oral administration.
Fire-fighting measures
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
Special hazards caused by the substance, its products of combustion or resulting gases:
Oxides of phosphorus
Phosphorus trihydride (phosphine)
Carbon monoxide
Carbon dioxide (CO2)
Protective equipment:
Wear a positive-pressure supplied-air respirator with full facepiece.
Additional information:
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Person-related safety precautions:
Ensure adequate ventilation
Wear protective clothing.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water should be disposed of in accordance with official regulations.
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
Special hazards caused by the substance, its products of combustion or resulting gases:
Oxides of phosphorus
Phosphorus trihydride (phosphine)
Carbon monoxide
Carbon dioxide (CO2)
Protective equipment:
Wear a positive-pressure supplied-air respirator with full facepiece.
Additional information:
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Person-related safety precautions:
Ensure adequate ventilation
Wear protective clothing.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water should be disposed of in accordance with official regulations.
Accidental release measures
Personal Precautions:
Ventilate the area
Remove all sources of ignition.
Use personal protective equipment.
Measures for environmental protection:
Contain any spill with dikes or absorbents to prevent migration and entry into sewers or streams.
Avoid release to the environment.
Prevent from entering sewer system, surface water or soil.
Measures for cleaning/collecting:
Pick up mechanically.
Dispose of the material collected according to regulations.
Avoid dust formation.
Additional information:
No dangerous substances are released.
Ventilate the area
Remove all sources of ignition.
Use personal protective equipment.
Measures for environmental protection:
Contain any spill with dikes or absorbents to prevent migration and entry into sewers or streams.
Avoid release to the environment.
Prevent from entering sewer system, surface water or soil.
Measures for cleaning/collecting:
Pick up mechanically.
Dispose of the material collected according to regulations.
Avoid dust formation.
Additional information:
No dangerous substances are released.
Handling and storage
Advice on safe handling
Avoid dust formation. Compounds containing phenolic groups may potentially have severe dust explosivity rating. Employ bonding, grounding, venting and explosion relief provisions in accord with accepted engineering practices in process operations capable of generating dust and/or static electricity. Explosion hazard can be reduced by good housekeeping, prevention of the escape of dust from process equipment and prevention of accumulation of dust on overhead, horizontal surfaces. In addition, a continuing effort should be made to control ignition sources. Local exhaust is needed at source of dust. Mechanical ventilation is
recommended.
General:
Keep away from sources of ignition - No smoking.
Use only with adequate ventilation.
Use personal protective equipment as required.
Avoid contact with skin, eyes and clothing.
Avoid breathing dust.
Avoid repeated exposure.
Avoid prolonged contact.
Avoid creating dust.
Use only in well-ventilated areas.
Keep away from open flames, hot surfaces and sources of ignition.
Ensure all equipment is electrically grounded before beginning transfer operations.
Storage
Requirements for storage areas and containers
Keep container tightly closed.
Keep in a well-ventilated place.
Keep in a dry, cool and well-ventilated place.
Keep container tightly closed.
Keep away from flames and sparks.
Keep away from heat and sources of ignition.
Further information on storage conditions
Incompatible with oxidizing agents.
Incompatible with strong acids and bases.
Other data
Stable under normal conditions
Avoid dust formation. Compounds containing phenolic groups may potentially have severe dust explosivity rating. Employ bonding, grounding, venting and explosion relief provisions in accord with accepted engineering practices in process operations capable of generating dust and/or static electricity. Explosion hazard can be reduced by good housekeeping, prevention of the escape of dust from process equipment and prevention of accumulation of dust on overhead, horizontal surfaces. In addition, a continuing effort should be made to control ignition sources. Local exhaust is needed at source of dust. Mechanical ventilation is
recommended.
General:
Keep away from sources of ignition - No smoking.
Use only with adequate ventilation.
Use personal protective equipment as required.
Avoid contact with skin, eyes and clothing.
Avoid breathing dust.
Avoid repeated exposure.
Avoid prolonged contact.
Avoid creating dust.
Use only in well-ventilated areas.
Keep away from open flames, hot surfaces and sources of ignition.
Ensure all equipment is electrically grounded before beginning transfer operations.
Storage
Requirements for storage areas and containers
Keep container tightly closed.
Keep in a well-ventilated place.
Keep in a dry, cool and well-ventilated place.
Keep container tightly closed.
Keep away from flames and sparks.
Keep away from heat and sources of ignition.
Further information on storage conditions
Incompatible with oxidizing agents.
Incompatible with strong acids and bases.
Other data
Stable under normal conditions
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not restricted.
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not restricted.
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- Not restricted.
Shipping information
- Proper shipping name and description:
- Not restricted.
- Chemical name:
- Not restricted.
- Labels:
- Not restricted.
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not restricted.
Shipping information
- Proper shipping name and description:
- Not restricted.
- Chemical name:
- Not restricted.
- Labels:
- Not restricted.
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Ingredients with limit values that require monitoring at the workplace:
None:
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium
efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm). Selection of the glove material should be made on consideration of the penetration times, rates of diffusion and the degradation.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protective boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment.
Wash thoroughly after handling.
Wash contaminated clothing before reuse.
None:
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium
efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm). Selection of the glove material should be made on consideration of the penetration times, rates of diffusion and the degradation.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protective boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment.
Wash thoroughly after handling.
Wash contaminated clothing before reuse.
Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Materials to avoid: Strong acids and oxidizing agents. Strong bases.
Conditions to Avoid Avoid dust formation.
Stability: Compounds containing phenolic groups may potentially have severe dust explosivity rating. Employ bonding, grounding, venting and explosion relief provisions in accord with accepted engineering practices in process operations capable of generating dust and/or static electricity. Explosion hazard can be reduced by good housekeeping, prevention of the escape of dust from process equipment and prevention of accumulation of dust on overhead, horizontal surfaces. In addition, a continuing effort should be made to control ignition sources.
Hazardous decomposition products: Oxides of carbons and phosphorus.
No decomposition if used according to specifications.
Materials to avoid: Strong acids and oxidizing agents. Strong bases.
Conditions to Avoid Avoid dust formation.
Stability: Compounds containing phenolic groups may potentially have severe dust explosivity rating. Employ bonding, grounding, venting and explosion relief provisions in accord with accepted engineering practices in process operations capable of generating dust and/or static electricity. Explosion hazard can be reduced by good housekeeping, prevention of the escape of dust from process equipment and prevention of accumulation of dust on overhead, horizontal surfaces. In addition, a continuing effort should be made to control ignition sources.
Hazardous decomposition products: Oxides of carbons and phosphorus.
Disposal considerations
Waste from residues / unused products: Residual chemical should be disposed by incineration or by other modes of disposal in compliance with local legislation.
Contaminated packaging: Contaminated packaging material should be treatedequivalent to residual chemical. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local legislation.
Contaminated packaging: Contaminated packaging material should be treatedequivalent to residual chemical. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local legislation.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
