Reaction product of {mixture of [poly(1~4)chlorosulfonylphthalocyaninato-N29,N30,N31,N32]copper(Ⅱ) and [poly(1~3) chlorosulfonyl (tribenzo[b,g,l]pyrido[2,3-q]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)] copper(Ⅱ) and [poly(1~2) chlorosulfonyl (dibenzo[b,g(or b,l)]dipyrido [2,3(or 3,2)-l,q(or g,q)]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)] copper(Ⅱ) and [monochlorosulfonyl (benzo[b]tripyrido [2,3(or 3,2)-g,l,q]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)]copper(Ⅱ) }and 2-[4-(2-aminoethylamino)-6-(benzylamino)-1,3,5-triazin-2-ylamino]benzene-1,4-disulfonic acid, and ammonia water and sodium chloride

Auto flammability

Administrative data

Endpoint:

relative self-ignition temperature (solids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

11 February 2011 – 27 April 2011

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: This study has been performed according to an EC guideline and in compliance with GLP principles.

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2011

Report date:

2011

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.16 (Relative Self-Ignition Temperature for Solids)

Version / remarks:

(Official Journal of the European Union no. L142, May 31, 2008)

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Test material

Test material information

Constituent 1

Reference substance name:

E-C104

IUPAC Name:

E-C104

Details on test material:

- Name of test material (as cited in study report): E-C104
- Description: Blue powder
- Batch: MB-1
- Test substance storage: At room temperature protected from light
- Stability under storage conditions: Stable
- Expiry date: 23 December 2015

Results and discussion

Relative self-ignition temperature (solids)

Remarks on result:

other: not self-ignitable (see discussion below)

Any other information on results incl. tables

An exothermic effect was observed. It started at an oven temperature of 319°C but the temperature of the test substance did not reach 400°C during this effect. During further heating, the temperature of the test sample remained above the temperature of the oven. The test substance reached 400°C at an oven temperature of 362°C and a maximum temperature of 432°C.

According to the guideline, a test substance is self-ignitable when the sample temperature reaches 400°C by self-heating with a sharp temperature rise. Because no sharp temperature rise was observed the test substance is considered „not self-ignitable‟.

During the experiment, the test substance had turned into a green/blue and partially black residue. It confirms that the test substance had decomposed and/or reacted during the experiment.

Applicant's summary and conclusion

Conclusions:

The self-ignition temperature of E-C104 was determined using a temperature programmed laboratory oven, a stainless steel wire mesh cube, NiCr/NiAl thermocouples and a temperature recording device. Based on the results obtained the test substance is considered "not self-ignitable".