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Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
21 July 2016 to 22 July 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
Purity: >95%; UVCB
Batch: NBN
Expiry date: 01 June 2018
Key result
Auto-ignition temperature:
>= 273 - <= 283 °C
Atm. press.:
>= 100.6 - <= 101.7 kPa
Remarks on result:
other:
Remarks:
The auto-ignition temperature of tall oil reaction products with diethylenetriamine was determined to be of 278 ± 5 ˚C

The test item has been determined to have an auto-ignition temperature of 278 ± 5 ˚C

Test temperature (ºC)

Test volume (μL)

Ignition delay (s)

Observations

200 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

250 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

300 (clean flask)

70

23

An orange flame. Grey fumes were emitted.

290

70

31

An orange flame. Grey fumes were emitted.

280

70

>300

No ignition. Grey fumes were emitted.

282

70

>300

No ignition. Grey fumes were emitted.

284

70

44

An orange flame. Grey fumes were emitted.

282 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

282 (clean flask)

200

>300

No ignition. Grey fumes were emitted.

282 (clean flask)

400

38

An orange flame. Grey fumes were emitted.

280 (clean flask)

400

51

An orange flame. Grey fumes were emitted.

278 (clean flask)

400

>300

No ignition. Grey fumes were emitted.

278 (clean flask)

600

36

An orange flame. Grey fumes were emitted.

279 (clean flask)

600

>300

No ignition. Grey fumes were emitted.

276 (clean flask)

800

>300

No ignition. Grey fumes were emitted.

276 (clean flask)

1000

>300

No ignition. Grey fumes were emitted.

276 (clean flask)

1200

>300

No ignition. Grey fumes were emitted.

276 (clean flask)

1400

>300

No ignition. Grey fumes were emitted.

276 (clean flask)

1400

>300

No ignition. Grey fumes were emitted.

 

Conclusions:
The test item has been determined to have an auto-ignition temperature of 278 ± 5 ˚C
Executive summary:

The auto-ignition temperature of tall oil reaction products with diethylenetriamine was determined to be 278 ± 5 ˚C. The study was conducted according to Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008.

Description of key information

The auto-ignition temperature of tall oil reaction products with diethylenetriamine CAS 68140-14-7 EC 268-766-5 was determined to be 278 ± 5 ˚C. The study was conducted according to Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
278 °C

Additional information