Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 500-332-0 | CAS number: 153195-44-9
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Skin contact: Immediately flush skin with water while removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Destroy contaminated leather items such as shoes, belts, and watchbands. Suitable emergency safety shower facility should be immediately available.
Eye contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Skin contact: Immediately flush skin with water while removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Destroy contaminated leather items such as shoes, belts, and watchbands. Suitable emergency safety shower facility should be immediately available.
Eye contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.
Fire-fighting measures
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location.
Accidental release measures
Personal precautions, protective equipment and emergency procedures: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep upwind of spill. Ventilate area of leak or spill. Use appropriate safety equipment.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.
Methods and materials for containment and cleaning up: Contain spilled material if possible. Absorb with materials such as: Sand. Collect in suitable and properly labeled containers.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.
Methods and materials for containment and cleaning up: Contain spilled material if possible. Absorb with materials such as: Sand. Collect in suitable and properly labeled containers.
Handling and storage
Precautions for safe handling: Do not get in eyes. Avoid prolonged contact with eyes, skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Do not swallow. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage, including any incompatibilities: Store in a cool, dry place.
Conditions for safe storage, including any incompatibilities: Store in a cool, dry place.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2327
Shipping information
- Proper shipping name and description:
- TRIMETHYLHEXAMETHYLENEDIAMINES
- Labels:
- Hazard Identification Number: 80
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2327
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Marine transport (UN RTDG/IMDG)
- UN number:
- 2327
Shipping information
- Proper shipping name and description:
- TRIMETHYLHEXAMETHYLENEDIAMINES
Special provisions / remarks
- Remarks:
- Not considered as marine pollutant based on available data.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 22327
Shipping information
- Proper shipping name and description:
- Trimethylhexamethylenediamines
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Exposure controls / personal protection
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.
Individual protection measures
Eye/face protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent.
Skin protection
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Avoid gloves made of: Polyvinyl alcohol ("PVA"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if handling at elevated temperatures without sufficient ventilation, use an approved air-purifying respirator.
Use the following CE approved air-purifying respirator: Organic vapor cartridge, type A (boiling point >65 ºC)
Individual protection measures
Eye/face protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent.
Skin protection
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Avoid gloves made of: Polyvinyl alcohol ("PVA"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if handling at elevated temperatures without sufficient ventilation, use an approved air-purifying respirator.
Use the following CE approved air-purifying respirator: Organic vapor cartridge, type A (boiling point >65 ºC)
Stability and reactivity
Chemical stability: Stable under recommended storage conditions.
Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Generation of gas during decomposition can cause pressure in closed systems. Reaction with carbon dioxide may form an amine carbamate. Smoke may be generated depending on vapor pressure of mixture. Product absorbs carbon dioxide from the air.
Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Acids. Acrylates. Alcohols. Aldehydes. Halogenated hydrocarbons. Ketones. Nitrites. Avoid contact with metals such as: Brass. Bronze. Copper. Copper alloys.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Aromatic compounds. Ammonia. Ethylenediamine. Volatile amines. Hydrocarbons. Phenolics.
Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Generation of gas during decomposition can cause pressure in closed systems. Reaction with carbon dioxide may form an amine carbamate. Smoke may be generated depending on vapor pressure of mixture. Product absorbs carbon dioxide from the air.
Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Acids. Acrylates. Alcohols. Aldehydes. Halogenated hydrocarbons. Ketones. Nitrites. Avoid contact with metals such as: Brass. Bronze. Copper. Copper alloys.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Aromatic compounds. Ammonia. Ethylenediamine. Volatile amines. Hydrocarbons. Phenolics.
Disposal considerations
Waste treatment methods
This product, when being disposed of in its unused and uncontaminated state should be treated as a hazardous waste according to EC Directive 2008/98/EC. Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste. For used, contaminated and residual materials additional evaluations may be required. Do not dump into any sewers, on the ground, or into any body of water.
The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. Contact the authorized waste disposal services.
This product, when being disposed of in its unused and uncontaminated state should be treated as a hazardous waste according to EC Directive 2008/98/EC. Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste. For used, contaminated and residual materials additional evaluations may be required. Do not dump into any sewers, on the ground, or into any body of water.
The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. Contact the authorized waste disposal services.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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