Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.

Inhalation
Possible discomfort: severe irritation of mucous lining (nose, throat, eyes), cough, sneezing, flow of tears
Move victims into fresh air.
If breathing difficulties occur:
Keep patient half sitting with upper body raised.
Call a physician immediately.

Skin contact
Wash off affected area immediately with plenty of water for at least 15 minutes.
With liposoluble substances, products, or preparations, continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.

Eye contact
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).

Ingestion
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
When dealing with caustic substances, notify emergency physician immediately.

Most important symptoms and effects, both acute and delayed

Symptoms
Irritation of skin and mucous membranes
Causes burns.
daze,
Headache, vertigo, somnolence (sleepiness), nausea.
Aspiration in the lungs might cause a chemical pneumonia.
Aspiration may cause pulmonary oedema and pneumonitis.
Health injuries may be delayed.

Hazards
Strongly irritating to corrosive.Harmful by inhalation, in contact with skin and if swallowed.Vapours may cause drowsiness and dizziness.

Indication of any immediate medical attention and special treatment needed
In case of substances with high water solubility, inhalation of vapors, aerosols, mists, and smoke from caustic substances, products, and preparations, as well as caustic gases, results in irritations up to formation of necrosis in the upper respiratory tract.
The initial focus is on the local action: signs of irritation of the respiratory tract such as coughing, burning behind the sternum, tears, burning in the eyes or nose.
There is a fundamental risk of acute toxic pulmonary edema!
In case of substances with low water solubility, only slight local irritations may appear at first, but after several hours of latency without symptoms, may develop into increasingly labored breathing and cyanosis as a result of a delayed pulmonary edema.
There is a danger of underestimating the severity of the intoxication!

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media: high volume water jet

Special hazards arising from the substance or mixture
Hazardous fumes in fires, specific to the product:
nitrogen oxides (NOx)
Carbon oxides

Advice for firefighters
Water for fire fighting must not be introduced in the sewer system, subsoil, or surface waters. Assure that there are sufficient fire water retaining facilities Contaminated fire fighting water must be disposed of in conformity with the regulations of the local authorities.
Fire residues should be disposed of in accordance with the regulations.
In case of fire: wear a self contained respiratory apparatus
Wear suitable protective clothing.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
Keep unauthorized persons away.

Environmental precautions
Do not allow substance to enter soil, bodies of water or sewage canals.
Should not be released into the environment.
To be disposed of in compliance with existing regulations.

Methods and material for containment and cleaning up
Use mechanical handling equipment.
Transfer into suitable containers.

Reference to other sections
Wear personal protective equipment

Handling and storage

Precautions for safe handling
Avoid residues of the product on the containers.
Observe the rules usually applicable when handling chemicals.

Conditions for safe storage, including any incompatibilities

Advice on protection against fire and explosion
Take precautionary measures against static charges, keep away from sources of ignition.

Storage
Further information
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.

Transport information

Land transport (ADR/RID)

UN number:
UN 3263
Shippingopen allclose all
Class:
8
Classification code:
C8
Packaging group:
III
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3263
Shippingopen allclose all
Class:
8
Classification code:
C8
Packaging group:
III
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3263
Proper shipping name and description:
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2,2,6,6-Tetramethylpiperidinooxy)
Chemical name:
2,2,6,6-Tetramethylpiperidinooxy
Class:
8
Packaging group:
III
EmS code:
F-A, S-B
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3263
Proper shipping name and description:
Corrosive solid, basic, organic, n.o.s. (2,2,6,6-Tetramethylpiperidinooxy)
Chemical name:
2,2,6,6-Tetramethylpiperidinooxy
Class:
8
Packaging group:
III
Labels:
8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters

DNEL/DMEL values
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.

PNEC values
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.


Exposure controls
Engineering measures
Provide sufficient air exchange and/or exhaust in work rooms.

Personal protective equipment
Respiratory protection
Use suitable respiratory protection where aerosols/vapours are generated.
use respiratory equipment with suitable filter (gas filter filter type A, particle filter) or wear a self contained respiratory apparatus
Note time limit for wearing respiratory protective equipment.

Hand protection
Applies to handling for longer periods or of large amounts
Glove material: Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0,65 mm
Method: DIN EN 374
Applies to handling for brief periods or of small amounts
Glove material: Nitrile, for example, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0,11 mm
Method: DIN EN 374

Eye protection
Safety glasses with side-shields conforming to EN166

Skin and body protection
Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.

Hygiene measures
Avoid contact with skin and eyes.
Wash off immediately in the event of contact with the skin (rinsing agent: glycol polyethylene 400), rinse off afterwards with copious amounts of water.
Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.
Take off clothing and shoes contaminated with product. Clean before reuse.

Protective measures
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
Handle in accordance with good industrial hygiene and safety practice.

Stability and reactivity

Reactivity
No further information available

Chemical stability
No further information available

Possibility of hazardous reactions
No further information available

Conditions to avoid
No further information available

Incompatible materials
No further information available

Hazardous decomposition products
Decomposition products in combustion and thermal decomposition
Splitting agent:
Amines
Ammonia
Acetone

Disposal considerations

Waste treatment methods

Product
Disposal according to local authority regulations.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.

Uncleaned packaging
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.