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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
18 - 19 Jan 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Qualifier:
according to guideline
Guideline:
other: OECD 113 Screening test for thermal stability and stability in air
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Phthalide
EC Number:
201-744-0
EC Name:
Phthalide
Cas Number:
87-41-2
Molecular formula:
C8H6O2
IUPAC Name:
1,3-dihydro-2-benzofuran-1-one

Results and discussion

Small-scale preliminary tests
Key result
Parameter:
other: A differential scanning calorimetry (DSC) was performed under nitrogen.
Remarks on result:
other: The heat of decomposition was above the threshold value of 500 J/g. However, the exothermal effect in the DSC measurements was a very broad peak. This suggests rather a slow decomposition than a violent reaction.

Any other information on results incl. tables

Two DSC measurements in closed glass crucibles with the test item showed an endothermal effect in the temperature range of 60-85 °C and two exothermal effects. The first exothermal effect occurred in the temperature range of 135-185 °C with a maximum energy release of 36 J/g. The second exothermal effect in the temperature range of 380-480 °C showed a maximum energy release of 694 J/g. However, the exothermal effect in the DSC measurements was a very broad peak. This suggests rather a slow decomposition than a violent reaction. Therefore, the test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14.

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Executive summary:

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No 440/20078, Methode A.14.