Registration Dossier
Registration Dossier
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EC number: 231-727-3 | CAS number: 7704-99-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
* Description of first aid measures
- General advice : First Aid responders should pay attention to self-protection and use the recommended protective clothing. Take off contaminated clothing and shoes immediately.
Move out of dangerous area. Keep warm and in a quiet place.
- If inhaled : Provide fresh air. If not breathing, give artificial respiration. Keep the victim calm and in a semi-upright position. Call a physician immediately.
- In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Consult a physician.
- In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.
- If swallowed : Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician immediately.
• Most important symptoms and effects, both acute and delayed
- Symptoms : Respiratory disorders. Irritation
•Indication of any immediate medical attention and special treatment needed
- Treatment : Treat symptomatically. For specialist advice physicians should contact the Poisons. Information Service.
- General advice : First Aid responders should pay attention to self-protection and use the recommended protective clothing. Take off contaminated clothing and shoes immediately.
Move out of dangerous area. Keep warm and in a quiet place.
- If inhaled : Provide fresh air. If not breathing, give artificial respiration. Keep the victim calm and in a semi-upright position. Call a physician immediately.
- In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Consult a physician.
- In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.
- If swallowed : Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician immediately.
• Most important symptoms and effects, both acute and delayed
- Symptoms : Respiratory disorders. Irritation
•Indication of any immediate medical attention and special treatment needed
- Treatment : Treat symptomatically. For specialist advice physicians should contact the Poisons. Information Service.
Fire-fighting measures
•Extinguishing media
-Suitable extinguishing media : Dry extinguishing media based on NaCl or pulverized limestone.
-Unsuitable extinguishing media: Water, Halons, Carbon dioxide (CO2)
•Special hazards arising from the substance or mixture
-Specific hazards during firefighting: Heat generation can lead to spontaneous combustion. Dust can form an explosive mixture in air. Burning product decomposes water instantaneously (explosion). May form toxic gases on heating or in case of fire. Hydrogen. Zirconium dioxide
•Advice for firefighters
-Special protective equipment for firefighters: Wear full protective clothing and self-contained breathing apparatus.
-Further information : Use a water spray to cool fully closed containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
-Suitable extinguishing media : Dry extinguishing media based on NaCl or pulverized limestone.
-Unsuitable extinguishing media: Water, Halons, Carbon dioxide (CO2)
•Special hazards arising from the substance or mixture
-Specific hazards during firefighting: Heat generation can lead to spontaneous combustion. Dust can form an explosive mixture in air. Burning product decomposes water instantaneously (explosion). May form toxic gases on heating or in case of fire. Hydrogen. Zirconium dioxide
•Advice for firefighters
-Special protective equipment for firefighters: Wear full protective clothing and self-contained breathing apparatus.
-Further information : Use a water spray to cool fully closed containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
•Personal precautions, protective equipment and emergency procedures
-Personal precautions : Remove all sources of ignition. Ensure adequate ventilation. Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe dust. Keep people away from and upwind of spill/leak.
•Environmental precautions
-Environmental precautions : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.
•Methods and materials for containment and cleaning up
-Methods for cleaning up : Cover spilled material with limestone powder. Use mechanical handling equipment. Pick up and transfer to properly labelled containers. Adequate disposal
-Personal precautions : Remove all sources of ignition. Ensure adequate ventilation. Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe dust. Keep people away from and upwind of spill/leak.
•Environmental precautions
-Environmental precautions : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.
•Methods and materials for containment and cleaning up
-Methods for cleaning up : Cover spilled material with limestone powder. Use mechanical handling equipment. Pick up and transfer to properly labelled containers. Adequate disposal
Handling and storage
•Precautions for safe handling
-Advice on safe handling : Handle under inert gas. Keep under argon. Provide sufficient air exchange and/or exhaust in work rooms. Wear personal protective equipment. Avoid dust formation. Handle in accordance with good industrial hygiene and safety practice. In general, emissions are controlled and prevented by implementing an appropriate management system, including regular informing and training workers.
-Advice on protection against fire and explosion: Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Dust can form an explosive mixture in air. Take precautions against dust explosion. Use explosion-proof equipment. Heat generation can lead to spontaneous combustion.
•Conditions for safe storage, including any incompatibilities
-Requirements for storage areas and containers: Keep under argon. Keep containers tightly closed in a dry, cool and wellventilated place. Keep away from heat. Protect from moisture. Avoid contact with air/oxygen.
-Further information on storage conditions: Product is hygroscopic.
-Advice on common storage : Never allow product to get in contact with water during storage. Do not store near acids. Incompatible with oxidizing agents.
•Specific end use(s)
-Specific use(s) : Reducing agents, Alloy component., Pyrotechnics., Getter technology
-Advice on safe handling : Handle under inert gas. Keep under argon. Provide sufficient air exchange and/or exhaust in work rooms. Wear personal protective equipment. Avoid dust formation. Handle in accordance with good industrial hygiene and safety practice. In general, emissions are controlled and prevented by implementing an appropriate management system, including regular informing and training workers.
-Advice on protection against fire and explosion: Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Dust can form an explosive mixture in air. Take precautions against dust explosion. Use explosion-proof equipment. Heat generation can lead to spontaneous combustion.
•Conditions for safe storage, including any incompatibilities
-Requirements for storage areas and containers: Keep under argon. Keep containers tightly closed in a dry, cool and wellventilated place. Keep away from heat. Protect from moisture. Avoid contact with air/oxygen.
-Further information on storage conditions: Product is hygroscopic.
-Advice on common storage : Never allow product to get in contact with water during storage. Do not store near acids. Incompatible with oxidizing agents.
•Specific end use(s)
-Specific use(s) : Reducing agents, Alloy component., Pyrotechnics., Getter technology
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1437
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Marine transport (UN RTDG/IMDG)
- UN number:
- 1437
Shipping information
- Proper shipping name and description:
- ZIRCONIUM HYDRIDE
- Chemical name:
- ZIRCONIUM HYDRIDE
- Labels:
- 4.1
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1437
Shipping information
- Proper shipping name and description:
- Zirconium hydride
- Chemical name:
- Zirconium hydride
- Labels:
- 4.1
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Exposure controls / personal protection
•Engineering measures
Provide sufficient air exchange and/or exhaust in work rooms. Take precautionary measures against static discharges. Take precautions against dust explosion. Electrical equipment should be protected to the appropriate standard.
•Personal protective equipment
-Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Half mask with a particle filter P2 (EN 143).
-Hand protection : Glove material: Wear suitable gloves. Protective gloves complying with EN 374 and protective gloves complying with EN 659. Glove material: Flame retardant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. The exact break through time can be obtained from the protective glove producer and this has to be observed. Protective gloves have to be replaced at the first sign of deterioration.
-Eye protection : Tightly fitting safety goggles. Eye protection (EN 166).
-Skin and body protection : Flame retardant protective clothing according to DIN EN 531.
-Hygiene measures : Take off contaminated clothing and shoes immediately. Avoid contact with skin, eyes and clothing. Do not breathe dust. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Keep away from food, drink and animal feedingstuffs.
-Protective measures : Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower. Handle in accordance with good industrial hygiene and safety practice.
•Environmental exposure controls
-General advice : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.
Provide sufficient air exchange and/or exhaust in work rooms. Take precautionary measures against static discharges. Take precautions against dust explosion. Electrical equipment should be protected to the appropriate standard.
•Personal protective equipment
-Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Half mask with a particle filter P2 (EN 143).
-Hand protection : Glove material: Wear suitable gloves. Protective gloves complying with EN 374 and protective gloves complying with EN 659. Glove material: Flame retardant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. The exact break through time can be obtained from the protective glove producer and this has to be observed. Protective gloves have to be replaced at the first sign of deterioration.
-Eye protection : Tightly fitting safety goggles. Eye protection (EN 166).
-Skin and body protection : Flame retardant protective clothing according to DIN EN 531.
-Hygiene measures : Take off contaminated clothing and shoes immediately. Avoid contact with skin, eyes and clothing. Do not breathe dust. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Keep away from food, drink and animal feedingstuffs.
-Protective measures : Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower. Handle in accordance with good industrial hygiene and safety practice.
•Environmental exposure controls
-General advice : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.
Stability and reactivity
•Reactivity
Risk of violent reaction, risk of explosion.
•Chemical stability
Sensitive to air, product is sensitive to moisture, do not heat the product.
•Possibility of hazardous reactions
-Hazardous reactions : Burning product decomposes water instantaneously (explosion). Reacts with oxidizing substances instantaneously (explosion). Dust can form an explosive mixture in air. Heat generation can lead to spontaneous combustion. Strong reaction with acids.Oxidizing agents
•Conditions to avoid
-Conditions to avoid : Keep away from open flames, hot surfaces and sources of ignition. Avoid shock and friction. Keep away from heat. Avoid dust formation. Protect from direct sunlight. Static discharge. Avoid contact with air/oxygen. Protect from moisture. Product is hygroscopic.
•Incompatible materials
-Materials to avoid : Acids. Oxidizing agents
•Hazardous decomposition products
-Risk of decomposition. : Heating can release vapours which can be ignited.
-Thermal decomposition : > 400 °C To avoid thermal decomposition, do not overheat.
Risk of violent reaction, risk of explosion.
•Chemical stability
Sensitive to air, product is sensitive to moisture, do not heat the product.
•Possibility of hazardous reactions
-Hazardous reactions : Burning product decomposes water instantaneously (explosion). Reacts with oxidizing substances instantaneously (explosion). Dust can form an explosive mixture in air. Heat generation can lead to spontaneous combustion. Strong reaction with acids.Oxidizing agents
•Conditions to avoid
-Conditions to avoid : Keep away from open flames, hot surfaces and sources of ignition. Avoid shock and friction. Keep away from heat. Avoid dust formation. Protect from direct sunlight. Static discharge. Avoid contact with air/oxygen. Protect from moisture. Product is hygroscopic.
•Incompatible materials
-Materials to avoid : Acids. Oxidizing agents
•Hazardous decomposition products
-Risk of decomposition. : Heating can release vapours which can be ignited.
-Thermal decomposition : > 400 °C To avoid thermal decomposition, do not overheat.
Disposal considerations
•Waste treatment methods
-Product : Dispose of in accordance with local regulations.
-Contaminated packaging : Dispose of in accordance with local regulations.
-Waste Code : Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
-Product : Dispose of in accordance with local regulations.
-Contaminated packaging : Dispose of in accordance with local regulations.
-Waste Code : Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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