Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 211-185-4 | CAS number: 632-79-1
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Repeated dose toxicity: oral
Administrative data
- Endpoint:
- sub-chronic toxicity: oral
- Type of information:
- migrated information: read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- key study
- Study period:
- 1993
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: The study was performed by the US National Toxicology Program on the related substance tetrachlorophthalic anhydride.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 993
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- EPA OPPTS 870.3100 (90-Day Oral Toxicity in Rodents)
- GLP compliance:
- yes
- Limit test:
- no
Test material
- Reference substance name:
- Tetrachlorophthalic anhydride
- EC Number:
- 204-171-4
- EC Name:
- Tetrachlorophthalic anhydride
- Cas Number:
- 117-08-8
- IUPAC Name:
- 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione
- Details on test material:
- Obtained from Aldrich Chemical Company, Milwaukee, WI. 99% in purity.
Constituent 1
Test animals
- Species:
- rat
- Strain:
- Fischer 344
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- Obtained from Simonsen Laboratories, Gilroy, CA.
Acclimated ~14 prior to start of study.
Age at study inititation: Rats (6 wks), Mice (5 wks)
Assigned to groups randomlly.
Fed NIH-07 Open Formula Mash ad libitum
Rats house 5/cage; Mice individually
Temperature 67-77 degrees F
30-70% relative humidity
Minimum of 10 air changes/hr.
Lighting 12 hr/d.
Administration / exposure
- Route of administration:
- oral: gavage
- Vehicle:
- corn oil
- Analytical verification of doses or concentrations:
- yes
- Duration of treatment / exposure:
- 13 weeks
- Frequency of treatment:
- Once daily, 5 d/wk, for 13 weeks.
Doses / concentrations
- Remarks:
- Doses / Concentrations:
0, 94, 187, 375, 750, 1500 mg/kg bw
Basis:
other:
- No. of animals per sex per dose:
- 10M/10F/dose
- Control animals:
- yes, concurrent vehicle
- Details on study design:
- wieghed weekly. necropsies on all animals. Measured weight of brain, heart, right kidney, liver, lung, spleen, right testis, and thymus. Complete histopathology on controls, all animals in the highest dose group with at least 60% survival, and on all animals including those that dies or were killed moribund before the end of the studies in the higher dose groups. Target tissues ID'd, and examined in all animals from the lower dose groups until a no effect level was determined. all gross lesions also examined histologically. In rats, the target organ was the kidney and was evaluated in all males and females in all dose groups. No target organs were ID'd in mice.
Clinical pathology performed in rats i nteh 0, 94, 375 and 1500 mg/kg groups on days 6, 20, and at the end of the study. Hematology performed in all animals at end of study. blood collected via retroorbital sinus after CO2 anesthesia.
Sperm morphology in male rats from the 0, 94, 375 and 750 mg/kg groups. Vaginal cytology performed on female rats from the 0, 94, 375 and 1500 mg/kg groups. Similar exams on mice in hte 0, 94, 375 and 1500 mg/kgg. Methods were those of Morrissey et al. 1988.
Results and discussion
Results of examinations
- Clinical signs:
- effects observed, treatment-related
- Description (incidence and severity):
- 5 M rats, 1500 mg/kg, died during wks 5-8 due to toxicity. 2 F rats, 1 each @ 750 and 1500 mg/kg died during wks 6 - 10 due to xicity.
- Mortality:
- mortality observed, treatment-related
- Description (incidence):
- 5 M rats, 1500 mg/kg, died during wks 5-8 due to toxicity. 2 F rats, 1 each @ 750 and 1500 mg/kg died during wks 6 - 10 due to xicity.
- Body weight and weight changes:
- effects observed, treatment-related
- Description (incidence and severity):
- Mean final body weights and weight gains of male rats in the 375, 750 and 1500 mg/kg groups and F rats in all dose groups were less than those of controls
- Food consumption and compound intake (if feeding study):
- effects observed, treatment-related
- Description (incidence and severity):
- Decreased in rats of all groups.
- Food efficiency:
- not examined
- Water consumption and compound intake (if drinking water study):
- not examined
- Ophthalmological findings:
- not examined
- Haematological findings:
- no effects observed
- Clinical biochemistry findings:
- no effects observed
- Urinalysis findings:
- not examined
- Organ weight findings including organ / body weight ratios:
- effects observed, treatment-related
- Description (incidence and severity):
- Absolute and relative kidney weights increased in dose-dependednt manner in female rats. In males increased relative kidney weights from 187 mg/kg and above.
- Gross pathological findings:
- no effects observed
- Histopathological findings: non-neoplastic:
- effects observed, treatment-related
- Description (incidence and severity):
- In male rats, renal tubule degnerative changes characterized by tubule epitheial necrosis at the higher dose levels and tubule dilation at lower dose levels. Necrosis of the tubule epithelium was seen in the nmajority ofmale and female rats in the 1500 m
- Details on results:
- Sperm morphology and vaginal cytology evaluations in rats revealed no changes between control and treated animals.
Effect levels
- Dose descriptor:
- LOAEL
- Effect level:
- 94 mg/kg bw/day (actual dose received)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- other: Clear evidence of renal toxicity.
Target system / organ toxicity
- Critical effects observed:
- not specified
Applicant's summary and conclusion
- Conclusions:
- Clear evidence of renal toxicity in rats was observed following administration of tetrachlorophthalic anhydride in corn oil by gavage for 13 weeks. The no-observed-adverse-effect level for histopathological lesions in this tissue was not achieved with doses as low as 94 mg/kg/d.
- Executive summary:
Clear evidence of renal toxicity in rats was observed following administration of tetrachlorophthalic anhydride in corn oil by gavage for 13 weeks. The no-observed-adverse-effect level for histopathological lesions in this tissue was not achieved with doses as low as 94 mg/kg/d.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.