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Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Administrative data

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Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Basic data given. Certificate of Analysis.
Qualifier:
according to guideline
Guideline:
other: UIL 1046
Principles of method if other than guideline:
Test method based on UIL 1046.
GLP compliance:
no
Type of method:
pour point
Melting / freezing pt.:
-24 °C
Atm. press.:
ca. 1 013 hPa
Remarks on result:
other: Pour point

No data available for pressure but assumed to be determined at normal pressure.

Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1997-07-14 - 1997-07-22
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Qualifier:
according to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
GLP compliance:
yes
Type of method:
method to determine freezing temperature
Key result
Remarks on result:
not determinable
Remarks:
In a triplicate experiment it was found that the test substance has no defined freezing point. Please see free text field: Any other information on results incl. tables.

In a triplicate experiment it was found that the test substance has no defined freezing point.

The test substance became cloudy at a temperature of -30.6 °C (242.4 K), -26.8 °C ( 246.2 K) and -25 °C (248 K) in test 1, 2 and 3.

The test substance became viscous at approximately -34 °C (239 K), -40 °C (233 K) and -32.8 °C (240.2 K) in test 1, 2 and 3, respectively. An in the test substance inserted stirrer could not be moved at a temperature of -50.7 °C (222.3 K), -56.1 °C (216.9 K) and -51.2 °C (221.8 K) in test 1, 2 and 3, respectively.

The temperature fall was < 5 K/min.

In conclusion, no freezing temperature can be determined. The viscosity of the test substance increases with decreasing temperature until finally, the test substance is completely solid

Description of key information

No freezing temperature could be determined, because the viscosity of test substance increases with decreasing temperature until the test substance is completely solid.
Pour point: -24 °C at ca. 1013 hPa

Key value for chemical safety assessment

Additional information

The melting point of the substance Fatty acids, C16-18 (even numbered) and C18-unsatd., branched and linear, di- and triesters with trimethylolpropane (former CAS 85005 -23 -8) was determined according to OECD guideline 102 / EU method A.1 using the method to determine freezing temperature.

Another determination of pour point according a company internal method (-24 °C) is supporting.