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Physical & Chemical properties

Auto flammability

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Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From 26 August 2016 to 31 August 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
IEC 60079-4 (Electrical apparatus for explosive gas atmospheres. Part 4: Method of test for ignition temperature)
Version / remarks:
1987
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
378 °C
Atm. press.:
>= 101.2 - <= 102.2 kPa

Table: Results of the auto-ignition temperature measurements

 

 Test temperature (ºC)  Test volume (μL)  Ignition delay (s)  Observations
 200 (clean flask)  70  >300 No ignition. Grey fumes were emitted. 
 250 (clean flask)  70  >300  No ignition. Grey fumes were emitted.
 300 (clean flask)  70  >300  No ignition. Grey fumes were emitted.
 350  70  >300  No ignition. Grey fumes were emitted.
 400  70  6 An orange flame. Grey fumes were emitted. 
 390 (clean flask)  70  7  An orange flame. Grey fumes were emitted.
 380 (clean flask)  70  10  An orange flame. Grey fumes were emitted.
 370 (clean flask)  70  >300  No ignition. Grey fumes were emitted.
 372  70  >300  No ignition. Grey fumes were emitted.
 374  70  >300  No ignition. Grey fumes were emitted.
 376  70  >300  No ignition. Grey fumes were emitted.
 378  70  14  An orange flame. Grey fumes were emitted.
 376 (clean flask)  70  >300  No ignition. Grey fumes were emitted.
 376 (clean flask)  200  >300  No ignition. Grey fumes were emitted.
 376 (clean flask)  400  >300  No ignition. Grey fumes were emitted
 376 (clean flask)  600  >300  No ignition. Grey fumes were emitted.
 376 (clean flask)  800 >300   No ignition. Grey fumes were emitted.
 376 (clean flask)  1000  >300  No ignition. Grey fumes were emitted.
Conclusions:
The auto-ignition temperature of the substance was determined to be 378°C (at 101-102 kPa ).
Executive summary:

The auto-ignition temperature of the substance at 101 -102 kPa was determined to be 378°C in a GLP study according to EC A.15 and IEC 79-4.

Description of key information

The auto-ignition temperature of the substance at 101-102 kPa was determined to be 378°C in a GLP study according to EC A.15 and IEC 79-4.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
378 °C

Additional information