Registration Dossier

Administrative data

First-aid measures

- Inhalation: Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Give oxygen. First aider needs to protect
himself. Call a physician immediately.
- Skin contact: Take off all contaminated clothing immediately. After contact with skin, wash immediately with plenty of soap and water. Call a
physician immediately.
- Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.
- Ingestion: Call a physician immediately. Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person.

Fire-fighting measures

- Suitable extinguishing media: Dry powder, Carbon dioxide (CO2), Dry sand, Cement
- Unsuitable extinguishing media: Water, Foam
- Specific hazards during firefighting : Heating or fire can release toxic gas.
- Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus.
- Further information: Use water spray to cool unopened containers.

Accidental release measures

- Personal precautions: Use respirator when performing operations involving potential exposure to vapour of the product.
- Environmental precautions: Do not flush into surface water or sanitary sewer system.
- Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations.

Handling and storage

- Advice on safe handling: Avoid contact with skin and eyes. Provide sufficient air exchange and/or exhaust in work rooms.
- Advice on protection against fire and explosion: Take precautionary measures against static discharges.
- Requirements for storage areas and containers: Keep container tightly closed in a dry and well-ventilated place. To maintain product quality, do not store in heat or direct sunlight. Keep locked up.
- Further information on storage conditions: Conditions to avoid humid air and water
- Other data: Keep in a dry place.

Transport information

Land transport (ADR/RID)

UN number:
3264
Shippingopen allclose all
Class:
C1
Classification code:
88
Packaging group:
I
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3264
Shippingopen allclose all
Class:
C1
Classification code:
88
Packaging group:
I
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3264
Proper shipping name and description:
Corrosive liquid, acidic, inorganic, n.o.s. (Chlorosulfonyl isocyanate)
Chemical name:
Chlorosulfonyl isocyanate
Class:
8
Packaging group:
I
EmS code:
F-A, S-B
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3264
Proper shipping name and description:
Corrosive liquid, acidic, inorganic, n.o.s. (Chlorosulfonyl isocyanate)
Chemical name:
Chlorosulfonyl isocyanate
Class:
8
Packaging group:
I
Labels:
8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

- Respiratory protection: In the case of vapour formation use a respirator with an approved filter. Respirator with a vapour filter (EN 141) Respirator with ABEK filter.
- Hand protection: Nitrile rubber, break through time > 480 min. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
- Eye protection: Tightly fitting safety goggles, face-shield
- Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place. Rubber or plastic apron Rubber or plastic boots
- Hygiene measures: Wash hands before breaks and immediately after handling the product. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing and gloves, including the inside, before re-use.

Stability and reactivity

- Reactivity: Stable under recommended storage conditions.
- Chemical stability: Stable under normal conditions.
- Possibility of hazardous reactions: Water, amines and alcohols cause exothermic reactions. Stable under recommended storage conditions.
- Conditions to avoid: No data available
- Incompatible materials: Strong oxidizing agents
- Hazardous decomposition products: Sulphur oxides

Disposal considerations

- General advice: Do not flush into surface water or sanitary sewer system.
- Product: Dispose of in accordance with local regulations. Dissolution of product in toluene and burned in an suitable incinerator.
- Contaminated packaging: Do not re-use empty containers. Uncontrolled disposal or recycling of this packaging is not permitted and can be dangerous.