Registration Dossier
Registration Dossier
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EC number: 417-310-0 | CAS number: 72903-27-6
Explosiveness
Administrative data
Link to relevant study record(s)
- Endpoint:
- explosive properties of explosives
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- 29th September 1999 to 4th October 1999
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Remarks:
- Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of relevant results.
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.14 (Explosive properties)
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Remarks:
- Date of inspection: 23rd March 1998 Date of signature: 21st July 1998
- Parameter:
- other: More sensitive to shock than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: More sensitive to friction than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- not measured/tested
- Parameter:
- other: Explosive under influence of flame
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: Explosive (not specified)
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Interpretation of results:
- non explosive
- Remarks:
- Migrated information
- Conclusions:
- The test substance is not sensitive to heating and shock.
The substance is NOT classified as explosive according to Directive 67/548/EEC (DSD) criteria.
The test is inconclusive according to Regulation (EC) N°1272/2008 (CLP) criteria. - Executive summary:
Method: The explosive properties were determined based on EU Method A14 , for sensivity towards heating (Koenen test) and shock (BAM fall hammer), under GLP.
Result: ST 03 C 99 was determined not to have explosive properties with regard to thermal and shock sensitivity.
- Endpoint:
- explosive properties of explosives
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- the study does not need to be conducted because there are no chemical groups present in the molecule which are associated with explosive properties
- Justification for type of information:
- JUSTIFICATION FOR DATA WAIVING
In accordance with column 2 of REACh Annex VII, the study does not need to be conducted if there are no chemical groups associated with explosive properties present in the molecule. According to Regulation (EC) N°1272/2008 (CLP) criteria and screening procedure (as listed in appendix 6 to the UN Recommendations on the Transport of Dangerous Goods - Manual of Tests and Criteria (6th revised edition, 2015) or in the ECHA endpoint specific guidance on information requirements (R.7a, v6.0, July 2017, §R.7.1.11), NO REACTIVE GROUP was identified.
Then explosive properties are not anticipated, and the acceptance procedure for Class 1 explosives shall not apply, no further testing is required.
Referenceopen allclose all
Description of key information
Testing for explosive and self-reactive properties waived, based on chemical structure (CLP criteria).
Not explosive with regard to heat or shock sensitivity (experimental; DSD criteria).
Key value for chemical safety assessment
- Explosiveness:
- non explosive
Additional information
According to the screening procedure described in Regulation (EC) N°1272/2008 (CLP), the structure of the substance does not contain any chemical group associated with explosive or self-reactive properties.
Therefore, no further testing is required.
Moreover, a supporting experimental study for the determination of explosive properties, with regard to sensitivity towards heat and shock (friction not required for liquids), is available. However, this test conducted according to Directive 67/548/EEC (DSD) classification criteria cannot be extrapolated to CLP criteria, as the testing strategy and study design differ significantly. Nevertheless the Koenen tube test is common, and the negative result confirms that the substance is not sensitive to heat.
Justification for classification or non-classification
The test material is NOT classified as explosive according to DSD annex VI criteria, based on experimental results.
The test material is NOT classified as explosive nor self-reactive according to CLP criteria, based on the structural formula.Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
