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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study according to EC guideline.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1997
Report date:
1997

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
-
EC Number:
427-720-1
EC Name:
-
Cas Number:
26364-65-8
Molecular formula:
C4H5N3S
IUPAC Name:
[(1,3-thiazolidin-2-ylidene)amino]formonitrile
Details on test material:
name: Cyanamide, (4,5-dihydroxy-2-thiazolyl)-
molecular formula: C4 H5 N3 S
molecular weight: 127.2
physical state: solid
analytical purity: 99.8 %

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
other: More sensitive to shock than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: More sensitive to friction than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

Koenen Test Results    
Nozzle Diameter Reaction Initiation after Results
2 mm 34 sec No fragments, cartridge unchanged
2 mm 36 sec No fragments, cartridge unchanged
2mm 34 sec No fragments, cartridge unchanged
6 mm 32 sec No fragments, cartridge unchanged
6 mm 26 sec No fragments, cartridge unchanged
6 mm 28 sec No fragments, cartridge unchanged
Total duration of individual tests > 300 sec  

Drop-Weight Test Results    
Mass Drop Height Results
10kg 40 cm Negative; no optical change in product apparent
10kg 40cm Negative; no optical change in product apparent
10kg 40cm Negative; no optical change in product apparent
10kg 40cm Negative; no optical change in product apparent
10kg 40 cm Negative; no optical change in product apparent
10kg 40cm Negative; no optical change in product apparent
Result : six times negative    

Mechanical Sensitivity (Friction Mill)

Method: BAM friction mill as described in EC Guideline A.14

Pin pressure: 360 N

Result: Six times negative

Applicant's summary and conclusion

Conclusions:
2-Cyanimino-1,34hiazolidin' is not explosive in the sense of EC Guideline A.14 and is not subject to classification.