Registration Dossier
Registration Dossier
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EC number: 700-713-3 | CAS number: 83161-22-2
Explosiveness
Administrative data
- Endpoint:
- explosiveness
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2011
- Reliability:
- 1 (reliable without restriction)
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 011
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.14 (Explosive properties)
- Deviations:
- no
- GLP compliance:
- not specified
Test material
- Reference substance name:
- (2S,3R,4R,5R,6R)-2-methyl-6-(pentyloxy)oxane-3,4,5-triol
- EC Number:
- 700-713-3
- Cas Number:
- 83161-22-2
- Molecular formula:
- C11H22O5
- IUPAC Name:
- (2S,3R,4R,5R,6R)-2-methyl-6-(pentyloxy)oxane-3,4,5-triol
Constituent 1
Results and discussion
Small-scale preliminary testsopen allclose all
- Parameter:
- other: More sensitive to shock than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: More sensitive to friction than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: Explosive under influence of flame
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: Explosive (not specified)
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
Any other information on results incl. tables
As stated in the reference (Commission Regulation (EC) No 440/2008, Annex A.14, § 1.1) “the tests need not to be performed when available thermodynamic information (e.g. heat of formation, heat of decomposition) and/or absence of certain reactive groups in the structural formula estab-lishes beyond reasonable doubt that the substance is incapable of rapid decomposition with evolu-tion of gases or release of heat (i.e. the material does not present any risk of explosion).”
1. The determination of the thermal stability of the test substance by DSC (Differential Scanning Calorimetry) - Figure 1 showed that between 30°C and 400°C the exothermal decomposition en-ergy is about -595 kJ/kg and therefore slightly above the limit of -500 kJ/kg for exclusion given in the Regulation (EC) No 1272/2008 (CLP) of the European Parliament and of the Council of 16 De-cember 2008 on classification, labelling and packaging of substances and mixtures, Chapter 2.1.4.3. (c).
2. According to the chemical structure and the list of reactive groups that could have explosive properties (Bretherick’s Handbook of Reactive Chemical Hazards, Butterworths, 4th edition) it can be excluded that APRC 5 has explosive properties.
| Description | Thermal signal Range (°C) Peak-Temperature (°C) |
Emergy (kJ/Kg) |
| APRC5 | exo : 119 - 244, 166 exo : 247 -417, 271 |
exo : -88 exo : -507 |
Applicant's summary and conclusion
- Interpretation of results:
- non explosive
- Remarks:
- Migrated information
- Conclusions:
- APRC is not explosive
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