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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: see 'Remark'
Remarks:
The reliability is rated 2 because the study followed the standard guideline of reference (EU A.16 method), which describes a procedure designed to evaluate this endpoint. The results were reviewed for reliability and assessed as valid. Nevertheless no information was available wheter or not the study was conducted under GLP condition.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2011
Report date:
2011

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Bis and tris and tetra (4-{bis[4-(dimethylamino)phenyl]methylene}-N,N-dimethylcyclohexa-2,5-dien-1-iminium) [12,21-dihydro-29H,31H-phthalocyanine-bis and tris and tetrasulfonato-k4N29,N30,N31,N32]cuprate
EC Number:
700-615-0
Molecular formula:
BIS: C82H74N14CuS2O6 TRIS: C107H103N17CuS3O9 TETRA: C132H132N20CuS4O12
IUPAC Name:
Bis and tris and tetra (4-{bis[4-(dimethylamino)phenyl]methylene}-N,N-dimethylcyclohexa-2,5-dien-1-iminium) [12,21-dihydro-29H,31H-phthalocyanine-bis and tris and tetrasulfonato-k4N29,N30,N31,N32]cuprate
Details on test material:
- Name of test material (as cited in study report):Sepisol Fast Violet 3B
- Substance type: organocopper
- Appearance/Physical state: dark violet powder
- Lot/batch No.: 028942

Results and discussion

Relative self-ignition temperature (solids)
Relative self-ignition temperature:
ca. 303 °C
Remarks on result:
other: 1. Exothermal peak at 190°C-225°C .Peak maximum at oven temperature of 206°C. 2. Exothermal peak at 225°C-400°C. Oven temperature was 303°C as the sample temperature reached 400 °C
Remarks:
at atm. press. of 1.0 atm

Applicant's summary and conclusion

Conclusions:
Under the experimental condition, the self-ignition temperature of Sepisol Fast Violet 3B was defined to be 303°C.
Executive summary:

The purpose of this test was to provide preliminary information on the relative auto-flammability of Sepisol Fast Violet 3B at elevated temperatures following the EU method A.16.

Approximately 8 mL of the substance under test is placed in a piece of stainless wire mesh (2x2x2 cm) in an oven at room temperature. Temperature/time curve relating to conditions in the centre of the sample is recorded while the temperature of the oven is increased gradualy to 400 °C.

Under the experimental condition, the relative self-ignition temperature of Sepisol Violet 3B was found to be 303°C.