Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Vapour pressure

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
16.09.2010-16.11.2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
2006
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Version / remarks:
2008
Deviations:
no
GLP compliance:
yes
Type of method:
effusion method: vapour pressure balance
Temp.:
20 °C
Vapour pressure:
0 Pa
Key result
Temp.:
25 °C
Vapour pressure:
0 Pa
Temp.:
50 °C
Vapour pressure:
0 Pa

Thermal stability


The DSC-measurement in a closed glass crucible showed an endothermic effect in the temperature range of 70-90 °C, followed by two smaller endothermal signals.


 


Vapour pressure balance (effusion method)


The vapour pressure was measured in the temperature range of 23 °C to 122 °C. Above 72 °C a vapour pressure could be measured. The measured vapour pressures at the corresponding temperatures are listed in the following table:


















































Temperature / °C



Vapour pressure / hPa



71.6



3.1 x 10^-5



74.0



3.9 x 10^-5



89.7



2.6 x 10^-4



93.9



4.4 x 10^-4



98.4



7.2 x 10^-4



103.2



1.2 x 10^-3



107.8



1.8 x 10^-3



112.8



3.1 x 10^-3



117.2



4.5 x 10^-3



121.6



6.6 x 10^-3



The values for 20, 25 and 50 °C are calculated, using the Antoine constants A, B and C.


The following constants were determined: A=14.04607, B=-6395.43, C=273.15. Vapour pressures of 1.7*10^-8 hPa at 20 °C, 3.94*10^-8 hPa at 25 °C and 1.8*10^-6 hPa at 50 °C were determined.

Conclusions:
The vapour pressures of the test item were determined to be 1.7*10^-8 hPa at 20 °C, 3.94*10^-8 hPa at 25 °C and 1.8*10^-6 hPa at 50 °C.
Executive summary:

A study was performed according to OECD TG 104 and Commission Regulation (EC) No. 440/2008, method A.4 in order to determine the vapour pressure of the test item by using the effusion method (vapour pressure balance). The vapour pressure was measured at various temperatures between 23 and 122 °C. The vapour pressures of the test item at 20, 25 and 50 °C were extrapolated by using the Antoine constants. Vapour pressures of 1.7*10^-8 hPa at 20 °C, 3.94*10^-8 hPa at 25 °C and 1.8*10^-6 hPa at 50 °C were determined.

Description of key information

The vapour pressures of the test item were determined to be 1.7*10^-8 hPa at 20 °C, 3.94*10^-8 hPa at 25 °C and 1.8*10^-6 hPa at 50 °C.

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
25 °C

Additional information

A study was performed according to OECD TG 104 and Commission Regulation (EC) No. 440/2008, method A.4 in order to determine the vapour pressure of the test item by using the effusion method (vapour pressure balance). The vapour pressure was measured at various temperatures between 23 and 122 °C. The vapour pressures of the test item at 20, 25 and 50 °C were extrapolated by using the Antoine constants. Vapour pressures of 1.7*10^-8 hPa at 20 °C, 3.94*10^-8 hPa at 25 °C and 1.8*10^-6 hPa at 50 °C were determined.