Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
General information:
In case of accident or if you feel unwell seek medical advice immediately (show the label if possible).
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes and seek medical advice. Keep eyelids well open to rinse the whole eye
surface and eyelids with water. Continue to bathe eyes during transport to medical practitioner.
After contact with the skin:
Wash with plenty of water or soap and water; immediately remove all contaminated clothing. Seek medical advice and clearly
identify substance.
After inhalation:
Provide fresh air. Seek medical advice and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and produce
the label or packaging.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
Further toxicology information must be observed.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
extinguishing powder , foam , carbon dioxide .
Extinguishing media which must not be used for safety reasons:
water .
Special hazards arising from the substance or mixture
Hazardous combustion products: nitrous gases .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Environmental precautions
Prevent material from entering sewers or surface waters. Contain any fluid that runs out using suitable material (e.g. earth).
Methods and material for containment and cleaning up
Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations.
Further information:
Eliminate all sources of ignition.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.

Handling and storage

Precautions for safe handling
Precautions for safe handling:
Ensure adequate ventilation. Avoid contact with acids.
Precautions against fire and explosion:
Cool endangered containers with water. Flammable vapors may accumulate and form explosive mixtures with air in containers,
process vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from open
flames, heat and sparks.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
none known
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.

Transport information

Land transport (ADR/RID)

UN number:
2734
Proper shipping name and description:
Amine, flüssig, ätzend, entzündbar, n.a.g. (1-Methyl-N,N',N''-tris(1-
methylpropyl)silantriamin)
AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (1-Methyl-N,N',N''-tris(1-
methylpropyl)silanetriamine)
Class:
8 (3)
Packaging group:
II
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2734
Proper shipping name and description:
Amine, flüssig, ätzend, entzündbar, n.a.g. (1-Methyl-N,N',N''-tris(1-
methylpropyl)silantriamin)
AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (1-Methyl-N,N',N''-tris(1-
methylpropyl)silanetriamine)
Class:
8 (3)
Packaging group:
II
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2734
Proper shipping name and description:
Amines, liquid, corrosive, flammable, n.o.s. (1-Methyl-N,N',N''-tris(1-
methylpropyl)silanetriamine)
Chemical name:
Amines, liquid, corrosive, flammable, n.o.s. (1-Methyl-N,N',N''-tris(1-
methylpropyl)silanetriamine)
Class:
8 (3)
Packaging group:
II
Remarks
Bulk transport in tankers is not intended.

Air transport ICAO/IATA

UN number:
2734
Chemical name:
Amines, liquid, corrosive, flammable, n.o.s. (1-Methyl-N,N',N''-tris(1-
methylpropyl)silanetriamine)
Class:
8 (3)
Packaging group:
II
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm
13952-84-6 2-Butylamine AGW 6,1 2,0
Aminobutane AGW 6,1 2,0
108-88-3 Toluene AGW 190,0 50,0

Toluene (CAS no. 108-88-3): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German
AGW.

CAS No. Param. Value other material Time
108-88-3 TOLUOL 1,0 mg/l VOLLBLUT B
108-88-3 O-KRESOL 3,0 mg/l URIN B,C

Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not breathe vapours. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter K
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Skin protection
protective clothing . Where there is risk of splashing: protective clothing, protective goggles/face protection .
Exposure to the environment limited and controlled
Prevent material from entering surface waters and soil. Do not introduce large amounts into purification plants.

Stability and reactivity

Reactivity; Chemical stability; Possibility of hazardous reactions
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid
none known
Incompatible materials
Reacts with: water . Reaction causes the formation of: corrosive substances .
Hazardous decomposition products
Under the effect of humidity, water and protic agents: sec. butyl amine .

Disposal considerations

Waste treatment methods
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Small quantities may be disposed of by
incineration in an approved facility. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.