Reaction product of 3-[4-(2-aminoethylamino)-6-(4-sulfoanilino)-1,3,5-heterocycle-2-ylamino]benzensulfonic acid, ammonia water, sodium chloride and {mixture of [poly(1~4)chlorosulfonylphthalocyaninato-N29,N30,N31,N32]copper(II), [poly(1~3)chlorosulfonyl (tribenzo[b,g,l]pyrido[2,3-q]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)]copper(II),[poly(1~2)chlorosulfonyl(dibenzol[b,g(or b,l)dipyrido[2,3(or 3,2)-l,q (or g,q)]-5,10,15,20-tetraazaporphyrinato-N21,N22,N23,N24)] copper(II) and [monochlorosulfonyl(benzo[b]tripyridol[2,3(or 3,2)-g,lq]-5,10,15,20- tetraazaporphyrinato- N21,N22,N23,N24)] copper(II)

Surface tension

Administrative data

Endpoint:

surface tension

Type of information:

experimental study

Adequacy of study:

key study

Study period:

08 January 2009 to 07 February 2009

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of relevant results.

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2009

Report date:

2009

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.5 (Surface Tension)

Deviations:

yes

Remarks:

1.The surface tension result was not corrected using the Harkins-Jordan correction table as the correction is not applicable to the apparatus used. Once calibrated, the balance and ring assembly used in this test give a direct reading for surface tension

Principles of method if other than guideline:

The determination was carried out using a White Electrical Institute interfacial tension balance and a procedure based on the ISO 304 ring method. With the exception of the deviation mentioned above, the experimental procedure used complied with that specified in Method A5 Surface Tension of Commission Regulation (EC) No 440/2008 of 30 May 2008.

GLP compliance:

yes (incl. QA statement)

Remarks:

Date of inspection: 19 August 2008; Date of signature: 04 March 2009

Type of method:

ring method

Test material

Reference

Name:

Unnamed

Type:

Constituent

Details on test material:

Sponsor's identification : H-CB sodium salt
Description : blue solid
Purity : 94.8%
Lot number : MB-2
Date received : 04 December 2008
Storage conditions : room temperature in the dark

Results and discussion

Surface tension

Surface tension:

72.6 mN/m

Temp.:

21.5 °C

Conc.:

1 030 g/L

Any other information on results incl. tables

Calibration factor (φ)

The readings, temperatures and the corresponding calibration factors for glass double-distilled water are shown in the following table:

 

Reading (mN/m)	Temperature (^oC)	Literature Value (mN/m)	Calibration Factor (φ)
73.0	21.2	72.53	0.994
73.0	21.2	72.53	0.994
73.0	21.2	72.53	0.994
73.0	21.4	72.50	0.993
73.0	21.4	72.50	0.993
73.0	21.4	72.50	0.993
Mean Calibration Factor = 0.994

 

Sample solution readings

The readings, times and temperatures for the sample solution are shown in the following table:

 

Time (mins)	Reading (mN/m)	Temperature (^oC)
67	73.0	21.2
77	73.0	21.2
88	73.0	21.2
103	73.0	21.4
112	73.0	21.4

 

Mean reading                : 73.0 mN/m

Surface tension            : reading x calibration factor

                                   : 73.0 x 0.994

                                   : 72.6 mN/m

Temperature                 : 21.5 +/- 0.5^oC

pH of sample solution    : 6.8

Applicant's summary and conclusion

Conclusions:

The surface tension of a 1030 g/l solution of test material has been determined to be 72.6 mN/m at 21.5 +/- 0.5 Deg C. The test material is considered not to be a surface-active material.

Executive summary:

72.6 mN/m (1.03 x 10³g/l solution) at 21.5 +/- 0.5^oC, using a ring method based on ISO 304, Method A5 Surface Tension of Commission Regulation (EC) No 440/2008 of 30 May 2008. The test material is considered not to be a surface-active material.