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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures

• General information:

Personal protection for the First Aider.

Take affected persons out of danger area and lay down.

Immediately remove any clothing soiled by the product.

Remove breathing equipment only after contaminated clothing have been completely removed.

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours

after the accident the accident.

• After inhalation:

Supply fresh air or oxygen; call for doctor.

In case of unconsciousness place patient stably in side position for transportation.

If breathing stops, provide artificial respiration.

• After skin contact:

Clean with water and soap. If possible, also wash with polyethylene glycol 400.

Take off immediately all contaminated clothing

Call a doctor immediately.

• After eye contact:

Remove contact lenses.

Protect unharmed eye.

Rinse opened eye for several minutes under running water. Then consult a doctor.

• After swallowing:

Rinse out mouth and then drink plenty of water.

Induce vomiting and call for medical help.

Do not give alcohol, milk or fatty oils.

A person vomiting while laying on their back should be turned onto their side.

Never give anything to the mouth of an unconscious person.

• Information for doctor: No specific therapy is known.

• Most important symptoms and effects, both acute and delayed

Breathing difficulty

Headache

Dizziness

Cramp

Dizziness

Cyanosis

Methaemoglobinaemia

Unconsciousness

Nausea

Drowsiness

Vomiting

Fire-fighting measures

Extinguishing media

• Suitable extinguishing agents:

Use fire extinguishing methods suitable to surrounding conditions.

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

• For safety reasons unsuitable extinguishing agents: Water with full jet

• Special hazards arising from the substance or mixture

During heating or in case of fire poisonous gases are produced.

In case of fire, the following can be released:

Nitrogen oxides (NOx)

Carbon monoxide and carbon dioxide

• Advice for firefighters

• Protective equipment:

Do not inhale explosion gases or combustion gases.

Wear fully protective suit.

Wear self-contained respiratory protective device.

Additional information

Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

Collect contaminated fire fighting water separately. It must not enter the sewage system.

Accidental release measures

• Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Use respiratory protective device against the effects of fumes/dust/aerosol.

Avoid contact with any product

• Environmental precautions:

Do not allow to enter sewers/ surface or ground water.

Inform respective authorities in case of seepage into water course or sewage system.

Do not allow to penetrate the ground/soil.

In case of seepage into the ground inform responsible authorities.

• Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Send for recovery or disposal in suitable receptacles.

Dispose contaminated material as waste according to disposal considerations.

Ensure adequate ventilation.

Handling and storage

• Handling:

• Precautions for safe handling

Keep receptacles tightly sealed.

Ensure good ventilation/exhaustion at the workplace.

Open and handle receptacle with care.

Prevent formation of aerosols.

Restrict the quantity stored at the work place.

Wear suitable respiratory protective device when aerosols are formed.

• Information about fire - and explosion protection:

Keep respiratory protective device available.

Keep ignition sources away - Do not smoke.

Protect against electrostatic charges.

Fumes can combine with air to form an explosive mixture.

When heatet the product forms flammable fumes.

• Conditions for safe storage, including any incompatibilities

• Storage:

• Requirements to be met by storerooms and receptacles:

Provide solvent resistant, sealed floor.

Provide floor trough without outlet.

Prevent any seepage into the ground.

Store only in unopened original receptacles.

Store in a cool, dry place.

• Information about storage in one common storage facility:

Store away from feed and foodstuffs.

Do not store together with oxidizing and acidic materials.

• Further information about storage conditions:

Keep container tightly sealed.

Avoid contact with air / oxygen.

Protect from exposure to the light.

Store under lock and key and with access restricted to technical experts or their assistants only.

Store in the dark.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2294
Shipping information
Proper shipping name and description:
N-METHYLANILINE
Chemical name:
N-Methylaniline
Language:
English
Labels:
6.1, Enviromentally Hazardous
Special provisions / remarks
Special provisions:
CV13 CV28
Remarks:
Danger code: 60
Limited quantity:5 l
Packing instruction: P001, IBC03, LP01, R001
Mixed packing provision: MP19

Inland waterway transport (UN RTDG/ADN(R))

UN number:
2294
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2294
Shipping information
Proper shipping name and description:
N-METHYLANILINE
Chemical name:
N-Methylaniline
Labels:
6.1
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
2294
Shipping information
Proper shipping name and description:
N-METHYLANILINE
Chemical name:
N-Methylaniline
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Additional information about design of technical facilities: No further data; see item 7.

• Control parameters

• Ingredients with limit values that require monitoring at the workplace:

100-61-8 N-Methylaniline

WEL Long-term value: 2.2 mg/m³, 0.5 ppm Sk

• Additional information: The lists valid during the making were used as basis.

• Exposure controls

• Personal protective equipment:

• General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Avoid contact with the eyes and skin.

Do not inhale gases / fumes / aerosols.

Be sure to clean skin thoroughly after work and before breaks.

Ensure that washing facilities are available at the work place.

• Respiratory protection:

If vapours or aerosols occur wear suitable respiratory device.

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure

use self-contained respiratory protective device.

Short term filter device:

Filter A

• Protection of hands:

Chemicals resistant gloves.

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

Softening of the callus when wearing air-impermeable gloves is possible.

Check protective gloves prior to each use for their proper condition.

If only a short-term loading of the glove material by splashes is expected, tricoted gloves with higher

wearability for the better acceptance of the users are recommended.

After use of gloves apply skin-cleaning agents and skin cosmetics.

• Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality

and varies from manufacturer to manufacturer.

Fluorocarbon rubber (Viton)

Recommended thickness of the material: 0.4 mm

• Penetration time of glove material

Breakthrough time 8 h

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be

observed.

• As protection from splashes gloves made of the following materials are suitable:

Butyl rubber, BR

Fluorocarbon rubber (Viton)

• Not suitable are gloves made of the following materials:

Natural rubber, NR

Chloroprene rubber, CR

Nitrile rubber, NBR

PVC gloves

• Eye protection:

Safety glasses

• Body protection:

Protective work clothing

Boots

Apron

Use protective suit.

Selection of protective clothing is subject to the specific kind of work and the corresponding risk potential.

Stability and reactivity

• Reactivity

• Chemical stability

• Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications.

To avoid thermal decomposition do not overheat.

• Possibility of hazardous reactions

Reacts with strong acids and oxidizing agents.

Reacts with inorganic acid chlorides.

Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.

With nitrosing agents, nitrous acid, nitrites forming of nitrosamines possible.

• Conditions to avoid No further relevant information available.

• Incompatible materials:

oxidizing agents

Exposure to light.

• Hazardous decomposition products:

Danger of forming toxic pyrolysis products.

In case of fire, the following can be released:

Nitrogen oxides (NOx)

Carbon monoxide and carbon dioxide

• Additional information: light sensitive

Disposal considerations

· Waste treatment methods

· Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

Disposal must be made according to official regulations.

· European waste catalogue

16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST

16 03 00 off-specification batches and unused products

16 03 05* organic wastes containing dangerous substances

· Uncleaned packaging:

· Recommendation: Disposal must be made according to official regulations.