Phenyl methacrylate

GHS

General Information

Name:

phenyl methacrylate

Implementation:

EU

Remarks:

Classification proposal, deviant from classification according to Annex VI of Reg (EC) No 1272/2008; Index Number 607-134-00-4; monoalkyl or monoaryl or monoalkyaryl esters of methacrylic acid with the exception of those specified elsewhere in this Annex (Eye Irrit. 2; STOT SE 3; Skin Irrit. 2). Due to actual newer toxicological studies (see IUCLID5 dataset), the necessity for labelling withy respect to skin and eye irritation is now obsolete but labelling for skin sensitisation is necessary. No new data are available to contradict the existing Annex 6 entry labelling for STOT SE 3.
This classification entry is valid for all specifications entered in Chapter 1.2.

Related composition

Related composition:

PHENYL METHACRYLATE

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Reason for no classification:

data conclusive but not sufficient for classification

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data lacking

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data lacking

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data lacking

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data lacking

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Hazard category:

Acute Tox. 4

Hazard statement:

H302: Harmful if swallowed.

Acute toxicity - dermal

Reason for no classification:

data lacking

Acute toxicity - inhalation

Reason for no classification:

data lacking

Skin corrosion / irritation

Reason for no classification:

data conclusive but not sufficient for classification

Serious eye damage / eye irritation

Reason for no classification:

data conclusive but not sufficient for classification

Respiratory sensitisation

Reason for no classification:

data lacking

Skin sensitisation

Hazard category:

Skin Sens. 1B

Hazard statement:

H317: May cause an allergic skin reaction.

Aspiration hazard

Reason for no classification:

data lacking

Reproductive toxicity

Reason for no classification:

data lacking

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Reason for no classification:

data conclusive but not sufficient for classification

Carcinogenicity

Reason for no classification:

data lacking

1. Specific target organ toxicity - single (STOT-SE)

Hazard category:

STOT Single Exp. 3

Hazard statement:

H335: May cause respiratory irritation.

Affected organs:

other: Respiratory tract

Route of exposure:

inhalation

1. Specific target organ toxicity - repeated (STOT-RE)

Reason for no classification:

data lacking

Specific concetration limits

1.

Concentration range (%):

>= 10

Hazard categories:

STOT Single Exp. 3

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Reason for no classification:

data conclusive but not sufficient for classification

Hazardous to the aquatic environment (long-term)

Reason for no classification:

data conclusive but not sufficient for classification

Hazardous to the ozone layer

Reason for no classification:

data lacking

Labelling

Signal word:

Warning

Hazard pictogram

GHS07: exclamation mark

Hazard statements

H302: Harmful if swallowed.

H317: May cause an allergic skin reaction.

H335: May cause respiratory irritation.

Precautionary statements

P261: Avoid breathing dust/fume/gas/mist/vapours/spray.

Avoid breathing vapours.

P264: Wash ... thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P271: Use only outdoors or in a well-ventilated area.

P272: Contaminated work clothing should not be allowed out of the workplace.

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/... if you feel unwell.

P302+P352: IF ON SKIN: Wash with plenty of water/…

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P321: Specific treatment (see ... on this label).

P330: Rinse mouth.

P333+P313: If skin irritation or rash occurs: Get medical advice/attention.

P363: Wash contaminated clothing before reuse.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P405: Store locked up.

P501: Dispose of contents/container to ...

Dispose of contents/container to: hazardous waste in accordance with local, state or national legislation. Incinerate under approved controlled conditions, using incinerators suitable for the disposal of noxious organic waste.