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Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2001-02-22 - 2002.01-17
Reliability:
1 (reliable without restriction)
Qualifier:
according to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
Version / remarks:
pre-test: slower heating rate: >1 °C/min, main test: Start-Temp.: 250 °C
Deviations:
yes
Remarks:
pre-test: slower heating rate: >1 °C/min, main test: Start-Temp.: 250 °C
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Deviations:
yes
Remarks:
pre-test: slower heating rate: >1 °C/min, main test: Start-Temp.: 250 °C
Principles of method if other than guideline:
NA
GLP compliance:
yes (incl. QA statement)
Type of method:
capillary method
Remarks:
Metal block
Key result
Atm. press.:
1 013.25 hPa
Decomposition:
yes
Remarks:
before melting
Decomp. temp.:
250 °C
Sublimation:
no
Remarks on result:
other: normal atmospheric pressure

When introduced to the apparatus at 250 °C the test substance was observed to decompose before melting. The vigorous nature of the decomposition reaction was presumably a result of the liberation of oxygen from potassium monopersulfate.

Conclusions:
Using a linear heating rate of 1 °C/min the test substance was found to decompose before melting and therefore does not possess a melting point under the testing conditions (atmospheric pressure).
Executive summary:

Using a linear heating rate of 1 °C/min the test substance was found to decompose at before melting and therefore does not possess a melting point under the testing conditions (atmospheric pressure).


When introduced to the apparatus at 250 °C the test substance was observed to decompose before melting. The vigorous nature of the decomposition reaction was presumably a result of the liberation of oxygen from potassium monopersulfate. This reaction was not observed in the preliminary test as the test substance was heated up to 250 °C at a slower rate.

Description of key information

Using a linear heating rate of 1 °C/min the test substance was found to decompose before melting and therefore does not possess a melting point under the testing conditions (atmospheric pressure).

Key value for chemical safety assessment

Additional information