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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Remarks:
Non-GLP study but using standard test methods and with documentation.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Principles of method if other than guideline:
Approximately 50g of TiTDP (Lankromark LE406, Batch W005184) was heated in a glass beaker over a period of 3 hours.
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Triisotridecyl phosphite
EC Number:
278-758-9
EC Name:
Triisotridecyl phosphite
Cas Number:
77745-66-5
Molecular formula:
C39H81O3P
IUPAC Name:
tris(2-methylnonacosyl) phosphite
Details on test material:
Lankromark LE406, Batch W005184

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
> 213 °C
Atm. press.:
1 atm
Remarks on result:
not determinable because of methodological limitations

Any other information on results incl. tables

 

10.50 AM

125°C

Slight condensation

11.12 AM

158°C

Vapours seen

11.16 AM

162°C

Condensing on upper beaker

11.27 AM

170°C

Still vapour

11.40 AM

181°C

Still vapour liquid slightly cloudy

11.55 AM

189°C

Still vapour liquid slightly cloudy

1.02 P.M.

213°C

Heating stopped. Slightly more vapour and a ring of solid has formed due to decomposition – and the liquid is cloudy.

The test was terminated here.

Applicant's summary and conclusion

Conclusions:
The sample did not self /auto ignite 213°C in the presence of air.
Executive summary:

Auto ignition temperature > 213°C; substance decomposes.