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Environmental fate & pathways

Henry's Law constant

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Reference
Endpoint:
Henry's law constant
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment
Principles of method if other than guideline:
Thermodynamic column method of Brunner et al. 1990 applied [Brunner S, Hornung E, Santl H, Wolff E, Pringer OG, Altschuh J, Brueggemann R (1990) Henry´s law constants for polychlorinated biphenyls: Experimental determination and structure-property relationship. Environ Sci Technol 24, 1751 - 1754]
GLP compliance:
not specified
H:
0 dimensionless
Temp.:
25 °C
Atm. press.:
1 013 hPa
H:
0.087 Pa m³/mol
Temp.:
25 °C
Atm. press.:
1 013 hPa
ambient pressure
Executive summary:

The Henry's law constant (HLC) of m-cresol was measured with a column method at 25°C resulting in a HLC of 0.087 Pa m³/mol.

Description of key information

The experimentally determined Henry's law constant for m-cresol is 0.087 Pa*m³/mole at 25°C.

Key value for chemical safety assessment

Henry's law constant (H) (in Pa m³/mol):
0.087
at the temperature of:
25 °C

Additional information

The distribution of m-cresol between aqueous solution and air is described by the Henry’s law constant.

A thermodynamic method was used to determine the Henry's law constant of m-cresol. At 25°C a value of 0.087 Pa*m³/mol was obtained. This value indicates a low volatility for m-cresol from aqueous solution.