Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 609-386-0 | CAS number: 37288-11-2
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation
Effects: May cause allergic respiratory reaction. Irritating tot he respiratory system.
Symptoms: Shortness of breath, wheezing and coughing. The effect of inhalation may be delayed.
First Aid: Remove person to fresh air. If signs/symptoms continue, get medical attention. Show the safety data sheet to the doctor in attendance.
Skin contact
Effects: May cause slight irritation.
Symptoms: Slight irritation.
First Aid: Remove and wash contaminated clothing before re-use. Wash off immediately with plenty of water. If symptoms persist, call a doctor. Show the safety data sheet to the doctor in attendance.
Eye contact
Effects: May cause slight irritation.
Symptoms: Slight irritation.
First Aid: Hold eye open and rinse slowly and gently with water for 15-20 min. Remove contact lenses, if present, after the first five minutes, then continue rinsing the eye. If symptoms persist, call a doctor. Show the safety data sheet to the doctor in attendance.
Ingestion
Effects: Ingestion may cause gastro-intestinal irritation.
Symptoms: Irritation.
First Aid: Rinse mouth with water and drink plenty of water. If symptoms persist, call a doctor. Show the safety data sheet to the doctor in attendance.
Effects: May cause allergic respiratory reaction. Irritating tot he respiratory system.
Symptoms: Shortness of breath, wheezing and coughing. The effect of inhalation may be delayed.
First Aid: Remove person to fresh air. If signs/symptoms continue, get medical attention. Show the safety data sheet to the doctor in attendance.
Skin contact
Effects: May cause slight irritation.
Symptoms: Slight irritation.
First Aid: Remove and wash contaminated clothing before re-use. Wash off immediately with plenty of water. If symptoms persist, call a doctor. Show the safety data sheet to the doctor in attendance.
Eye contact
Effects: May cause slight irritation.
Symptoms: Slight irritation.
First Aid: Hold eye open and rinse slowly and gently with water for 15-20 min. Remove contact lenses, if present, after the first five minutes, then continue rinsing the eye. If symptoms persist, call a doctor. Show the safety data sheet to the doctor in attendance.
Ingestion
Effects: Ingestion may cause gastro-intestinal irritation.
Symptoms: Irritation.
First Aid: Rinse mouth with water and drink plenty of water. If symptoms persist, call a doctor. Show the safety data sheet to the doctor in attendance.
Fire-fighting measures
Suitable extinguishing media: Standard procedure for chemical fires; alcohol resistant foam, water spray, dry chemical or carbon dioxide.
Hazardous combustion products: On burning, this material may generate toxic gases of combustion such as oxides of carbon, nitrogen and sulphur (COx, NOx and SOx) just like any organic material.
Specific hazards arising from the chemical: May cause an allergic respiratory reaction.
Protective equipment and precautions for fire fighters: As in any fire, wear self-contained breathing apparatus and full protective gear.
Hazardous combustion products: On burning, this material may generate toxic gases of combustion such as oxides of carbon, nitrogen and sulphur (COx, NOx and SOx) just like any organic material.
Specific hazards arising from the chemical: May cause an allergic respiratory reaction.
Protective equipment and precautions for fire fighters: As in any fire, wear self-contained breathing apparatus and full protective gear.
Accidental release measures
Personal precautions
Wear suitable personal protection.
Respiratory Protection: Maintain adequate ventilation. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with a particle filter (EN 143). P3 filters are recommended.
Eye protection: Safety glasses with side-shields. Avoid contact with eyes.
Skin Protection: Wear protective gloves/clothing.
Hand Protection: Use protective gloves that meet the minimum requirements of EN420 when handling solid products. Gloves that meet the additional requirements of EN374-2 should be worn when handling of liquid products. Practical experience has shown that nitrile rubber, butyl rubber, natural rubber (latex) and polyvinyl chloride (PVC) gloves offer adequate protection. There is no additional material, thickness, or breakthrough time requirements. Chemical resistant gloves, as defined according to EN374-3 are not required.
Environmental precautions
Prevent the material from entering surface water or sanitary sewer system. Do not discharge directly to a water source. If accidental spillage or washings enter drains or watercourses contact the local Environmental Authorities
Methods for cleaning up
Use appropriate personal protection. Avoid contact with the product. Contain spilled product. Collect spilled material by non-dispersive methods or with a vacuum cleaner equipped with a high efficiency filter. After spillage avoid generating aerosols or dust from dried preparation. Do not sweep, brush, use compressed air, which can create aerosols. Avoid splashing and high pressure washing. Provide for sufficient ventilation. Wash with plenty of water.
Wear suitable personal protection.
Respiratory Protection: Maintain adequate ventilation. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with a particle filter (EN 143). P3 filters are recommended.
Eye protection: Safety glasses with side-shields. Avoid contact with eyes.
Skin Protection: Wear protective gloves/clothing.
Hand Protection: Use protective gloves that meet the minimum requirements of EN420 when handling solid products. Gloves that meet the additional requirements of EN374-2 should be worn when handling of liquid products. Practical experience has shown that nitrile rubber, butyl rubber, natural rubber (latex) and polyvinyl chloride (PVC) gloves offer adequate protection. There is no additional material, thickness, or breakthrough time requirements. Chemical resistant gloves, as defined according to EN374-3 are not required.
Environmental precautions
Prevent the material from entering surface water or sanitary sewer system. Do not discharge directly to a water source. If accidental spillage or washings enter drains or watercourses contact the local Environmental Authorities
Methods for cleaning up
Use appropriate personal protection. Avoid contact with the product. Contain spilled product. Collect spilled material by non-dispersive methods or with a vacuum cleaner equipped with a high efficiency filter. After spillage avoid generating aerosols or dust from dried preparation. Do not sweep, brush, use compressed air, which can create aerosols. Avoid splashing and high pressure washing. Provide for sufficient ventilation. Wash with plenty of water.
Handling and storage
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Ensure adequate ventilation. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is forme. Avoid accumulation of dust. Avoid breathing dust or spray mist. Conduct regular cleaning of equipment, work area and clothing.
Storage
Keep container tightly closed in a cool, dry and well-ventilated place. Temperature 0-25°C (32°F-77°F).
Storage conditions: In unbroken packaging - dry and protected from the sun.
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Ensure adequate ventilation. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is forme. Avoid accumulation of dust. Avoid breathing dust or spray mist. Conduct regular cleaning of equipment, work area and clothing.
Storage
Keep container tightly closed in a cool, dry and well-ventilated place. Temperature 0-25°C (32°F-77°F).
Storage conditions: In unbroken packaging - dry and protected from the sun.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not regulated as dangerous goods according to transport regulations (ADR/RID).
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not regulated as dangerous goods according to transport regulations.
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Marine transport (UN RTDG/IMDG)
- UN number:
- Not regulated as dangerous goods according to transport regulations (IMDG).
Shipping information
- Proper shipping name and description:
- Not regulated as dangerous goods according to transport regulations (IMDG).
- Chemical name:
- Not regulated as dangerous goods according to transport regulations (IMDG).
- Labels:
- Not regulated as dangerous goods according to transport regulations (IMDG).
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not regulated as dangerous goods according to transport regulations (ICAO/IATA).
Shipping information
- Proper shipping name and description:
- Not regulated as dangerous goods according to transport regulations (ICAO/IATA).
- Chemical name:
- Not regulated as dangerous goods according to transport regulations (ICAO/IATA).
- Labels:
- Not regulated as dangerous goods according to transport regulations (ICAO/IATA).
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Exposure controls / personal protection
Appropriate engineering controls:
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Hygiene measures:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection: Safety glasses with side shields.
Hand protection:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary. > 8 hours (breakthrough time): Nitril rubber, butyl rubber, neoprene, Viton®. Replace damaged gloves.
Skin and body: Chemical-resistant protective suit.
Respiratory protection : Wear dust protection mask P3.
Environmental exposure controls:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Advice on personal protection is applicable for high exposure levels. Select proper personal protection based on a risk assessment of the actual exposure situation.
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Hygiene measures:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection: Safety glasses with side shields.
Hand protection:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary. > 8 hours (breakthrough time): Nitril rubber, butyl rubber, neoprene, Viton®. Replace damaged gloves.
Skin and body: Chemical-resistant protective suit.
Respiratory protection : Wear dust protection mask P3.
Environmental exposure controls:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Advice on personal protection is applicable for high exposure levels. Select proper personal protection based on a risk assessment of the actual exposure situation.
Stability and reactivity
Stable under recommended storage conditions.
Disposal considerations
Dispose of in accordance with local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
